Further studies on the photoreactivities of ruthenium-nitrosyl complexes with terpyridyl ligands

被引：19

作者：

Sasaki, Isabelle ^{[1
,2
]}

Amabilino, Silvia ^{[1
]}

Mallet-Ladeira, Sonia ^{[1
]}

Tasse, Marine ^{[1
]}

Sournia-Saquet, Alix ^{[1
]}

Lacroix, Pascal G. ^{[1
]}

Malfant, Isabelle ^{[1
]}

机构：

[1] LCC, UPR 8241, 205 Route Narbonne, F-31077 Toulouse, France

[2] ISM, 351 Cours Liberat, F-33405 Talence, France

来源：

NEW JOURNAL OF CHEMISTRY | 2019年 / 43卷 / 28期

关键词：

EFFECTIVE CORE POTENTIALS; NITRIC-OXIDE NO; MOLECULAR CALCULATIONS; OXIDATION; PHOTORELEASE; DELIVERY; REACTIVITY; MECHANISM; RELEASE; AMINES;

D O I：

10.1039/c9nj02398d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This study focuses on the two cis/trans-(Cl,Cl)-[Ru(R-Phtpy)Cl-2(NO)](+) isomers, where the R group is a NEt2 substituent on the 4 '-position of the phenylterpyridine (Phtpy) moiety. The photophysical characteristic properties of the two isomers and those of one nitrosamine derivative are described. The NO release properties are evaluated and show that the cis isomer is the most efficient with a good quantum yield of NO release. The X-ray structures of three ruthenium-nitrosyl complexes and of a photoproduct are presented.

引用

页码：11241 / 11250

页数：10

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