Synthesis, Structures and Properties of Two Complexes Based on Benzimidazole or Benzothiazole Ligand

被引：6

作者：

Zhang Zhongqiang ^{[1
,2
]}

Di Di ^{[1
]}

Zhai Jingshuo ^{[2
]}

Wu Lili ^{[2
]}

Zhu Qinlei ^{[1
]}

Xu Yanqing ^{[1
]}

Huang Rudan ^{[1
]}

机构：

[1] Beijing Inst Technol, Minist Educ, Sch Chem, Key Lab Cluster Sci, Beijing 100081, Peoples R China

[2] Hengshui Univ, Dept Appl Chem, Hengshui 053000, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2014年 / 30卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Chemical synthesis; Crystal structure; Luminescence property; Magnetic property; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; BENZOTHIAZOLIN-2-YLIDENE COMPLEXES; MAGNETIC-PROPERTIES; DINUCLEAR; ARCHITECTURE; COPPER(II); COBALT(II); CU(II); COORDINATION;

D O I：

10.1007/s40242-014-3434-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two complexes, Co(Hbim)(2)(NCS)(2)(Hbim=benzimidazole)(1) and [Cu(Hbzt) SCN]n(Hbzt=benzothiazole) (2) were synthesized by the same synthesis method and characterized by elemental analysis, infrared spectroscopy(IR), thermogravimetric analysis(TGA), X-ray powder diffraction(XRPD) and single-crystal X-ray diffraction. The results from the single-crystal X-ray diffraction indicate that complex 1 is zero-dimensional(0D) framework and complex 2 is 2-dimensional(2D) framework. In complex 2, the 3-dimensional(3D) supermolecular architecture was built up by means of pi-pi stacking interaction, and two helical chains existed in its structure. The luminescence properties and the magnetic properties of the two complexes were investigated.

引用

页码：185 / 189

页数：5

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