Synthesis, Structures and Properties of Two Complexes Based on Benzimidazole or Benzothiazole Ligand

被引：6
|
作者：
Zhang Zhongqiang [1 ,2 ]
Di Di [1 ]
Zhai Jingshuo [2 ]
Wu Lili [2 ]
Zhu Qinlei [1 ]
Xu Yanqing [1 ]
Huang Rudan [1 ]
机构：
[1] Beijing Inst Technol, Minist Educ, Sch Chem, Key Lab Cluster Sci, Beijing 100081, Peoples R China
[2] Hengshui Univ, Dept Appl Chem, Hengshui 053000, Peoples R China
来源：
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2014年 / 30卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Chemical synthesis; Crystal structure; Luminescence property; Magnetic property; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; BENZOTHIAZOLIN-2-YLIDENE COMPLEXES; MAGNETIC-PROPERTIES; DINUCLEAR; ARCHITECTURE; COPPER(II); COBALT(II); CU(II); COORDINATION;
D O I：
10.1007/s40242-014-3434-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two complexes, Co(Hbim)(2)(NCS)(2)(Hbim=benzimidazole)(1) and [Cu(Hbzt) SCN]n(Hbzt=benzothiazole) (2) were synthesized by the same synthesis method and characterized by elemental analysis, infrared spectroscopy(IR), thermogravimetric analysis(TGA), X-ray powder diffraction(XRPD) and single-crystal X-ray diffraction. The results from the single-crystal X-ray diffraction indicate that complex 1 is zero-dimensional(0D) framework and complex 2 is 2-dimensional(2D) framework. In complex 2, the 3-dimensional(3D) supermolecular architecture was built up by means of pi-pi stacking interaction, and two helical chains existed in its structure. The luminescence properties and the magnetic properties of the two complexes were investigated.
引用
收藏
页码：185 / 189
页数：5
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