A novel one-dimensional manganese phosphomolybdate with rectangular cavities:: [H3N(CH2)4NH3] (H3O)2{[Mn(phen)2]4 [MnMov12O30(HPO4)6(H2PO4)2} • 4H2O

被引：37
|
作者：
Yuan, M
Wang, EB [1 ]
Lu, Y
Li, YG
Hu, CW
Hu, NH
Jia, HQ
机构：
[1] NE Normal Univ, Inst Polyoxometalate Chem, Dept Chem, Changchun 130024, Peoples R China
[2] Acad Sinica, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 07期
基金：
中国国家自然科学基金;
关键词：
manganese phosphomolybdate; one-dimensional chain; rectangular cavity; hydrothermal synthesis;
D O I：
10.1016/S1387-7003(02)00458-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel manganese phosphomolybdate, [H3N(CH2)(4)NH3](H3O)(2){[Mn(phen)(2)](4)[(MnMovO30)-O-12(HPO4)(6)(H2PO4)(2)]} . 4H(2)O 1, has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. The crystal data: triclinic, P (1) over bar, a = 14.172(7) Angstrom, b = 16.547(2) Angstrom, c = 16.679(3) Angstrom, alpha = 62.881(12)degrees, beta = 73.83(3)degrees, gamma = 88.81(3)degrees. X-ray crystallography shows that the [Mn(phen)(2)] fragments are covalently bonded to the [Mn(Mo6P4)(2)] dimers leading to a one-dimensional chain with rectangular cavities occupied by tetramethylene-diamine cations and water molecules. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码：505 / 508
页数：4
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