Impact of 1-Methylimidazole on Crystal Formation, Phase Transitions, and Glass Formation in a Zeolitic Imidazolate Framework

被引：15

作者：

Yu, Ya ^{[1
]}

Qiao, Ang ^{[1
,2
]}

Bumstead, Alice Mary ^{[3
]}

Bennett, Thomas D. ^{[3
]}

Yue, Yuanzheng ^{[1
,2
]}

Tao, Haizheng ^{[1
]}

机构：

[1] Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Peoples R China

[2] Aalborg Univ, Dept Chem & Biosci, DK-9220 Aalborg, Denmark

[3] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB3 0FS, England

来源：

CRYSTAL GROWTH & DESIGN | 2020年 / 20卷 / 10期

基金：

英国工程与自然科学研究理事会;

关键词：

METAL-ORGANIC FRAMEWORKS; STABILITY;

D O I：

10.1021/acs.cgd.0c00740

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We show that 1-methylimidazole (1-MeIm) can act as a modulator for the synthesis of the zeolitic imidazolate framework ZIF-4 [Zn(Im)(2)], since it affects the particle size, size distribution, morphology, and surface defects of the resultant product. This modulation has a strong impact on the polyamorphic phase transition, recrystallization, melting, and glass formation in ZIF-4 according to our detailed structural analysis and differential scanning calorimetric analysis. This work provides an effective route to tailor ZIF crystals with the desired characteristics and functionalities.

引用

页码：6528 / 6534

页数：7

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