Redox-active tetraruthenium metallacycles: reversible release of up to eight electrons resulting in strong electrochromism

被引：31

作者：

Fink, Daniel ^{[1
]}

Weibert, Bernhard ^{[1
]}

Winter, Rainer F. ^{[1
]}

机构：

[1] Univ Konstanz, Fachbereich Chem, Univ Str 10, D-78453 Constance, Germany

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 36期

关键词：

CENTERED MIXED-VALENCY; MOLECULAR RECTANGLES; COMPLEXES; SYSTEMS; DELOCALIZATION; TRIARYLAMINES; SUBSTITUENT; REDUCTION; OXIDATION; EXAMPLES;

D O I：

10.1039/c6cc00936k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetraruthenium macrocycles with 1,4-divinylphenylene and diarylaminesubstituted isophthalic acids as the sides display up to eight one-electron redox steps and rich electrochromic behaviour with strong absorptions of the dications in the near infrared and of the tetra-and hexacations at low energies in the visible.

引用

页码：6103 / 6106

页数：4

共 3 条

[1] Electrochromism of a bipolar reversible redox-active ferrocene-viologen linked ionic liquid
Tahara, Hironobu
Baba, Rei
Iwanaga, Kodai
Sagara, Takamasa
Murakami, Hiroto
[J]. CHEMICAL COMMUNICATIONS, 2017, 53 (16) : 2455 - 2458
[2] Reversible Multielectron Release from Redox-Active Three-Dimensional Molecular Barrels with Ruthenium-Alkenyl Moieties
Das, Rajorshi
Linseis, Michael
Scheerer, Stefan
Zoller, Katrin
Senft, Laura
Ivanovic-Burmazovic, Ivana
Winter, Rainer F.
[J]. INORGANIC CHEMISTRY, 2022, 61 (32) : 12662 - 12677
[3] Reversible Capture and Release of Cl2 and Br2 with a Redox-Active Metal-Organic Framework
Tulchinsky, Yuri
Hendon, Christopher H.
Lomachenko, Kirill A.
Borfecchia, Elisa
Melot, Brent C.
Hudson, Matthew R.
Tarver, Jacob D.
Korzynski, Maciej D.
Stubbs, Amanda W.
Kagan, Jacob J.
Lamberti, Carlo
Brown, Craig M.
Dinca, Mircea
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (16) : 5992 - 5997

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