Electrochromism of a bipolar reversible redox-active ferrocene-viologen linked ionic liquid

被引：48
|
作者：
Tahara, Hironobu [1 ]
Baba, Rei [1 ]
Iwanaga, Kodai [1 ]
Sagara, Takamasa [1 ]
Murakami, Hiroto [1 ]
机构：
[1] Nagasaki Univ, Grad Sch Engn, 1-14 Bunkyo, Nagasaki 8528521, Japan
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 16期
基金：
日本学术振兴会;
关键词：
ELECTROCHEMICAL PROPERTIES; DEVICES; TRANSPORT; CONDUCTION; DESIGN; PHASE; SALTS; FILMS;
D O I：
10.1039/c6cc09412k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A ferrocene-viologen linked "bipolar'' type redox-active ionic liquid ([FcC(11)VC(1)][TFSI](2)) was synthesized as an electrochromic (EC) material that functions without any other additives: solvents, supporting electrolytes and sacrificial agents. The efficiency of a prototype symmetrical EC cell was 70 cm(2) C-1 at 1.0 V. The EC process was stable even after over 10 000 potential cycles.
引用
收藏
页码：2455 / 2458
页数：4
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