Effect of chitin nanofibrils on electrospinning of chitosan-based composite nanofibers

被引:36
|
作者
Dobrovolskaya, Irina P. [1 ,2 ]
Yudin, Vladimir E. [1 ,2 ]
Popryadukhin, Pavel V. [1 ,2 ]
Ivan'kova, Elena M. [1 ,2 ]
Shabunin, Anton S. [2 ]
Kasatkin, Igor A. [3 ]
Morgantie, Pierfrancesco [4 ]
机构
[1] Russian Acad Sci, Inst Macromol Cpds, 31 Bolshoy Pr VO, St Petersburg 199004, Russia
[2] Peter Great St Petersburg Polytech Univ, Polytechnicheskaya Ul 29, St Petersburg 195251, Russia
[3] St Petersburg State Univ, 7-9 Univ Nab, St Petersburg 199034, Russia
[4] Federico II Univ Naples, Appl Cosmet Dermatol, Corso Umberto 1,40, I-80138 Napolei, Italy
基金
俄罗斯科学基金会;
关键词
Electrospinning; Chitin nanofibrils; Nanocomposite; Chitin/chitosan; Composite nanofibers; Structure; SCAFFOLD;
D O I
10.1016/j.carbpol.2018.03.074
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Electrical conductivity, surface tension and viscosity of chitosan-based composite nanofibers are reported. 20 wt. % of chitin nanofibrils introduced into a chitosan solution leads to increase in viscosity of the mixture; the effect of shear rate becomes more pronounced. This phenomenon is caused by the formation of cluster structures involving filler particles, and by orientation of chitin nanofibrils under the action of shear stresses in electromagnetic field. Presence of chitin facilitated formation of nanofibers in electric field and led to significant decrease in the amount of defects.
引用
收藏
页码:260 / 266
页数:7
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