ortho-Acetoxylation of Phosphonic and Phosphoric Monoacids via Pd(II) Catalysis

被引：50

作者：

Chan, Li Yan ^{[1
]}

Meng, Xiangjian ^{[1
]}

Kim, Sunggak ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 78卷 / 17期

关键词：

WADSWORTH-EMMONS REACTION; ARYL HYDROGEN PHOSPHATES; H BOND ACTIVATION; DIRECTING GROUP; ORTHO-ARYLATION; C-O; OLEFINATION; COMPLEXES; MECHANISM; OXIDATION;

D O I：

10.1021/jo4011188

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and efficient method is developed for Pd-catalyzed ortho-acetoxylation using organophosphates, namely, benzylic phosphonic and aryl phosphoric monoacids, as the directing group.

引用

页码：8826 / 8832

页数：7