A radical-based strategy for the synthesis of higher homologues of sinefungin

被引：0
|
作者：
Maria, EJ
da Silva, AD
Fourrey, JL [3 ]
机构：
[1] Univ Estadual N Fluminen, CCT, Lab Ciencias Quim, BR-28015620 Campos dos Goytacazes, RJ, Brazil
[2] Univ Fed Juiz De Fora, ICE, Dept Quim, BR-36036330 Juiz De Fora, MG, Brazil
[3] CNRS, Inst Chim Subst Nat, F-91198 Gif Sur Yvette, France
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2000年 / 2000卷 / 04期
关键词：
complex nucleoside; antibiotics; radical; Zn-Cu couple;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Homosinefungin 5, which can be considered as an analogue of S-adenosylmethionine (SAM) and of S-adenosylhomocysteine (SAH), has been synthesized by means of a sequence in which the key step was the addition of a radical, produced by the simple treatment of an iodide precursor with a zinc-copper couple, to suitably activated olefins.
引用
收藏
页码：627 / 631
页数：5
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