Thermodynamic characteristics of formation reactions of the vanadium(V) malonate complex

被引:0
|
作者
Romodanovskii, P. A. [1 ]
Vorob'ev, P. N. [1 ]
Dmitrieva, N. G. [1 ]
Gridchin, S. N. [1 ]
Orlova, T. D. [1 ]
机构
[1] Ivanovo State Univ Chem Technol, Ivanovo, Russia
关键词
Sodium compounds;
D O I
10.1134/S1070328409070021
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The coordination equilibria in the vanadium(V)-malonic acid system were studied by calorimetry. The heats of formation reactions of the complex VO2CH2(COO) (2) (-) at 298.15 K and I = 0.50, 0.75, and 1.00 (NaC1O(4)) were determined. The standard thermodynamic characteristics of the studied equilibria were calculated.
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页码:479 / 481
页数:3
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