Catalytic Activity of Rhodium Phosphide for Selective Hydrodeoxygenation of Phenol

被引：7

作者：

Kanda, Yasuharu ^{[1
]}

Chiba, Taiyo ^{[2
]}

Aranai, Ryusei ^{[3
]}

Yasuzawa, Toshiya ^{[3
]}

Ueno, Ren ^{[2
]}

Toyao, Takashi ^{[4
]}

Kato, Kazuo ^{[5
]}

Obora, Yasushi ^{[6
]}

Shimizu, Ken-ichi ^{[4
]}

Uemichi, Yoshio ^{[1
]}

机构：

[1] Muroran Inst Technol, Grad Sch Engn, Coll Environm Technol, Appl Chem Res Unit, 27-1 Mizumoto, Muroran, Hokkaido 0508585, Japan

[2] Muroran Inst Technol, Grad Sch Engn, Div Sustainable & Environm Engn, 27-1 Mizumoto, Muroran, Hokkaido 0508585, Japan

[3] Muroran Inst Technol, Dept Appl Sci, Fac Engn, 27-1 Mizumoto, Muroran, Hokkaido 0508585, Japan

[4] Hokkaido Univ, Inst Catalysis, N-21,W-10, Sapporo, Hokkaido 0010021, Japan

[5] Japan Synchrotron Radiat Res Inst, 1-1-1 Kouto, Sayo, Hyogo 6795198, Japan

[6] Kansai Univ, Dept Chem & Mat Engn, Fac Chem Mat & Bioengn, Suita, Osaka 5648680, Japan

来源：

CHEMISTRY LETTERS | 2019年 / 48卷 / 05期

关键词：

Rhodium phosphide; Phenol; Selective hydrodeoxygenation; NOBLE-METAL PHOSPHIDES; HYDRODESULFURIZATION; TEMPERATURE;

D O I：

10.1246/cl.181044

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Effect of P/Rh ratio and reduction temperature on catalytic activity and product selectivity of rhodium phosphide (Rh2P) for hydrodeoxygenation (HDO) of phenol was studied to develop production of feedstocks from sustainable resources. The Rh-0.8P (P/Rh = 0.5) catalyst after reduction at 650-700 degrees C showed the highest HDO conversion and benzene selectivity. High activity and selectivity would be due to formation of Rh2P structure and slightly positive charged Rh site.

引用

页码：471 / 474

页数：4

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