Synthesis of Cu3(PO4)2 • H2O based solid solutions through Co or Ni substitution for Cu

被引：0
|
作者：
Viter, V. N.
Nagornyi, P. G.
机构：
[1] Natl Acad Sci Ukraine, Vernadsky Inst Gen & Inorgan Chem, UA-03680 Kiev, Ukraine
[2] Shevchenko Natl Univ, UA-01033 Kiev, Ukraine
来源：
INORGANIC MATERIALS | 2006年 / 42卷 / 09期
关键词：
Solid Solution; Monoclinic Structure; Phosphate Anion; Substitutional Solid Solution; Monoclinic Symmetry;
D O I：
10.1134/S0020168506090123
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
New substitutional solid solutions have been synthesized: (Cu1-xCox)(3)(PO4)(2)center dot H2O (0 < x <= 0.20), (Cu1-xNix)(3)(PO4)(2)center dot H2O (0 < x <= 0.12), and (Cu1-yCoy)(3)(PO4)(2)center dot H2O (0.55 <= y <= 0.65). The first two solid solutions are isostructural with Cu-3(PO4)(2)center dot H2O (monoclinic symmetry, sp. gr. C2/c); the third solid solution also has a monoclinic structure, which is a Cu-3(PO4)(2)center dot H2O related superstructure. The lattice parameter b of (Cu1-yCoy)(3)(PO4)(2)center dot H2O (0.55 <= y <= 0.65) is almost twice that of (Cu1-xCox)(3)(PO4)(2)center dot H2O (0 < x <= 0.20), while their a and c parameters differ little. The solid solutions have been characterized by chemical analysis, x-ray diffraction, IR spectroscopy, and thermal analysis.
引用
收藏
页码：996 / 1001
页数：6
相关论文
共 50 条
  • [31] CU(CH3COO)2-C6H12N4-H2O, CU3(PO4)2-C6H12N4-H2O SYSTEMS AT 25 DEGREESC
    SALEEVA, NV
    ZHURNAL NEORGANICHESKOI KHIMII, 1974, 19 (11): : 3147 - 3149
  • [32] Hydrothermal synthesis and crystal structure of a hybrid material based on [Cu4(bPY)4(H2O)2(PO4)2]2+ and an α-Keggin polyoxoanion
    Lu, Y
    Wang, EB
    Guo, YQ
    Xu, XX
    Xu, L
    JOURNAL OF MOLECULAR STRUCTURE, 2005, 737 (2-3) : 183 - 187
  • [33] Metal Oxygen Connectivities in Cu(II) Complexes of Meso-2,3-dibromosuccinic Acid (H2DBrS): [Cu3(H2O)2(μ3–OH)2(μ2–OAc)2(DBrS)]⋅4H2O 1 and [Cu3(H2O)4(DBrS)2](DBrSM)⋅4H2O 2
    Wan-Dan Weng
    Yue-Qing Zheng
    Feng Jiang
    Qing-Jun Niu
    Hong-Lin Zhu
    Journal of Cluster Science, 2015, 26 : 1425 - 1438
  • [34] Functionalized magnetic lipase/Cu3(PO4)2 hybrid nanoflower: Synthesis, characterization, and enzymatic evaluation
    Anboo, Shamini
    Lau, Sie Yon
    Kansedo, Jibrail
    Yap, Pow-Seng
    Hadibarata, Tony
    Kamaruddin, Azlina Harun
    HELIYON, 2024, 10 (06)
  • [35] THERMOLYSIS OF CU3(NH4)2(P2O7)2.3.2(H2O)
    KOPILEVICH, VA
    SHCHEGROV, LN
    PANCHUK, TK
    ZHURNAL NEORGANICHESKOI KHIMII, 1992, 37 (10): : 2257 - 2264
  • [36] Solid and solution structures and DNA binding properties of [MII(4-CNpy)2(SO4)(H2O)3]•H2O for M = Cu, Co, Ni
    Bhattacharyya, Manjit K.
    Devi, P. Grihanjali
    Dasgupta, Dipak
    Bora, Sanchay J.
    Das, Birinchi K.
    POLYHEDRON, 2012, 35 (01) : 62 - 68
  • [37] On conditions of formation of Cu3(NH4)2(P2O7)2 ×3 H2O
    Kopilevich, V.A.
    Panchuk, T.K.
    Shchegrov, L.N.
    Zhurnal Neorganicheskoj Khimii, 1992, 37 (04):
  • [38] Synthesis and thermolysis of substitutional solid solutions (Cu1−yMy)2(OH)PO4·xH2O (x = 0.1−0.2; M = Zn, Co, Ni)
    V. N. Viter
    Russian Journal of Applied Chemistry, 2009, 82 : 2093 - 2097
  • [39] STUDIES OF THE (NI, MG)3(PO4)2.NH2O SOLID-SOLUTIONS
    ROJO, T
    LEZAMA, L
    ROJO, JM
    INSAUSTI, M
    ARRIORTUA, MI
    VILLENEUVE, G
    EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY, 1992, 29 (02): : 217 - 228
  • [40] Synthesis and Characterization of NH4V(Gly)3(PO4)2•H2O
    Wei, Bo
    Cao, Huiqun
    Sun, Jianmin
    Lv, Yujuan
    2009 3RD INTERNATIONAL CONFERENCE ON BIOINFORMATICS AND BIOMEDICAL ENGINEERING, VOLS 1-11, 2009, : 1000 - +
12345