Indium-mediated atom-transfer cyclizations and reductive cyclizations

被引：43
|
作者：
Yanada, R [1 ]
Nishimori, N [1 ]
Matsumura, A [1 ]
Fujii, N [1 ]
Takemoto, Y [1 ]
机构：
[1] Kyoto Univ, Grad Sch Pharmaceut Sci, Sakyo Ku, Kyoto 6068501, Japan
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 26期
关键词：
D O I：
10.1016/S0040-4039(02)00880-8
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Novel indium-mediated reactions have been studied. Treatment of iodoalkyne with In (0.5 equiv.) and I-2 (0.5 equiv.) in MeOH proanotes the atom-transfer 5-exo-cyclization. In contrast. the reaction with In (2 equiv.) and I-2 (I equiv.) gives rise to a reductive 5-exo-cyclized product. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：4585 / 4588
页数：4
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