Camelina Oil- and Linseed Oil-Based Polymers with Bisphosphonate Crosslinks

被引:26
|
作者
Kasetaite, Sigita [1 ]
Ostrauskaite, Jolita [1 ]
Grazuleviciene, Violeta [2 ]
Svediene, Jurgita [3 ]
Bridziuviene, Danguole [3 ]
机构
[1] Kaunas Univ Technol, Dept Organ Technol, LT-50254 Kaunas, Lithuania
[2] Aleksandras Stulginskis Univ, Dept Chem, LT-53361 Akademija, Kauno R, Lithuania
[3] Nat Res Ctr, Biodeteriorat Res Lab, LT-08412 Vilnius, Lithuania
关键词
biodegradable; biopolymers & renewable polymers; crosslinking; thermosets; VEGETABLE-OIL; SATIVA; DERIVATIVES; COPOLYMERS; BIODIESEL; BLENDS;
D O I
10.1002/app.40683
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Natural oils are the attractive biobased alternatives for petroleum derived chemicals in the production of polymers. A series of new biodegradable polymers based on epoxidized camelina oil was synthesized and investigated. The thermal, mechanical, swelling properties, hydrolysis, biodegradation, and bioresistance of the camelina oil-based polymers with bisphosphonate crosslinks were studied and compared with those of the analogous polymers based on epoxidized linseed oil. The dependence of the polymer properties on the density of crosslinks was observed. The obtained results showed that the properties of the camelina oil-based polymers are comparable with those of the linseed oil-based polymers and that camelina oil is a promising starting material for the synthesis of polymers. (C) 2014 Wiley Periodicals, Inc.
引用
收藏
页码:8536 / 8543
页数:8
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