Pd/C-catalyzed carbonylative C-H activation with DMF as the CO source

被引：44
|
作者：
Chen, Jianbin [1 ]
Natte, Kishore [1 ]
Wu, Xiao-Feng [1 ,2 ]
机构：
[1] Univ Rostock eV, Leibniz Inst Katalyse, D-18059 Rostock, Germany
[2] Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Zhejiang, Peoples R China
来源：
TETRAHEDRON LETTERS | 2015年 / 56卷 / 46期
关键词：
Heterogeneous catalyst; C-H activation; Carbonylation; CO surrogates; Heterocycle synthesis; MONOXIDE-FREE AMINOCARBONYLATION; OXIDATIVE AMINOCARBONYLATION; BOND ACTIVATION; ARYL HALIDES; PALLADIUM; CONSTRUCTION; CYCLIZATION; C(SP(2))-H; EFFICIENT;
D O I：
10.1016/j.tetlet.2015.09.142
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An interesting Pd/C-catalyzed carbonylative cyclization of N-arylpyridin-2-amine derivatives via C-H activation has been developed. With DMF as the CO source, the desired quinazolinones were formed in moderate to good yields with good functional group tolerance. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6413 / 6416
页数：4
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