Pd(0)-catalyzed domino C-N coupling/hydroamination/C-H arylation reactions: efficient synthesis and photophysical properties of azaindolo[1,2-f] phenanthridines

被引：9
|
作者：
Thang Ngoc Ngo [1 ,2 ]
Janert, Frank [1 ]
Ehlers, Peter [1 ]
Do Huy Hoang [1 ]
Tuan Thanh Dang [1 ]
Villinger, Alexander [1 ]
Lochbrunner, Stefan [3 ]
Langer, Peter [1 ,2 ]
机构：
[1] Univ Rostock, Inst Chem, Albert Einstein Str 3A, D-18059 Rostock, Germany
[2] Univ Rostock eV LIKAT, Leibniz Inst Katalyse, Albert Einstein Str 29A, D-18059 Rostock, Germany
[3] Univ Rostock, Inst Phys, Univ Pl 3, D-18051 Rostock, Germany
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2016年 / 14卷 / 04期
关键词：
FUSED PHENANTHRIDINES; SEMICONDUCTORS; DERIVATIVES; NK109;
D O I：
10.1039/c5ob02274f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of new 7- and 4-azaindolo[1,2-f] phenanthridines were synthesized by a domino Pd(0)-catalyzed reaction, which involves three sequential steps: C-N coupling, hydroamination, and intramolecular C-H arylation. The products show promising fluorescence properties with high quantum yields (12-65%).
引用
收藏
页码：1293 / 1301
页数：9
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