Facile and one-step preparation carbon quantum dots from biomass residue and their applications as efficient surfactants

被引:24
|
作者
Ren, Ruibo [1 ]
Zhang, Zeyu [1 ]
Zhao, Pinhui [1 ]
Shi, Jingtao [2 ]
Han, Kechao [1 ]
Yang, Ziqiao [1 ]
Gao, Dongxing [1 ]
Bi, Fei [1 ]
机构
[1] Shandong Jianzhu Univ, Sch Transportat Engn, 1000 Fengming Rd, Jinan 250101, Shandong, Peoples R China
[2] Petrochina Fuel Oil Co Ltd, Res Inst, Beijing, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon Quantum Dots; biomass; nano-sized surfactant; pickering emulsion; stability; ONE-POT CONVERSION; BLOCK-COPOLYMERS; PARTICLES; DRIVEN;
D O I
10.1080/01932691.2018.1475239
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Using biomass residue as a source of carbon precursors, a pyrolysis method was used to prepare biomass-derived luminescent Carbon Quantum Dots (CQDs). The prepared CQDs exhibited excellent fluorescence and luminescence properties and fluorescence behaviors of CQDs acquired at different pyrolysis temperatures varied. Importantly, the CQDs showed superior surface activity and the styrene-in-water Pickering emulsion prepared using the CQDs as nano-sized surfactant was highly stable: the higher the pyrolysis temperature the better the stability of the emulsion. In addition, there was no stratification found in the emulsion which was stabilized by the CQD500 (CQDs prepared at 500 degrees C) after holding for 72hours. This research provided an approach for preparing the surfactants of nano-sized particles in large scale. The CQDs prepared using the proposed methods are expected to have a high number of potential applications.
引用
收藏
页码:627 / 633
页数:7
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