Variable Nuclearity in Lanthanoid Coordination Chemistry

被引：12

作者：

Andrews, Philip C. ^{[1
]}

Hennersdorf, Felix ^{[1
]}

Junk, Peter C. ^{[2
]}

Thielemann, Dominique T. ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[2] James Cook Univ, Sch Pharm & Mol Sci, Townsville, Qld 4811, Australia

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 2014卷 / 17期

基金：

澳大利亚研究理事会;

关键词：

Lanthanides; Cage compounds; Coordination chemistry; Iodine; CLUSTER; COMPLEXES; POLYMERS; LIGAND;

D O I：

10.1002/ejic.201402115

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of lanthanoid and iodine containing compounds of formulae [Ln(IPhacac)(3)(dmf)(2)], [K(dmf)(2){Ln(IPhacac)(4)}]n and [Ln(5)(OH)(5)(IPhacac)(10)] {(IPhacac) = bis(para-iododibenzoyl)methanide} have been prepared and structurally characterised. X-ray crystallography establishes that the compounds exist as monomers [Ln(IPhacac)3(dmf)2] {Ln = Pr (1), Nd (2), Tb (5), Dy (6)} and [Yb(IPhacac)3(dmf)2][Yb(IPhacac)3(dmf)(H2O)] (7) (dmf = N,N-dimethylformamide), polymers [K(dmf)2{Ln(IPhacac)4}]n {Ln = Nd (2a), Eu (3a), Gd (4a), Tb (5a), Dy (6a)} and pentanuclear clusters [Ln(5)(OH)(5)(IPhacac)(10)] {Ln = Tb (5b), Dy (6b), Yb (7b)}.

引用

页码：2849 / 2854

页数：6

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