Lanthanoid tetrazole coordination complexes

被引:36
|
作者
Massi, Massimiliano [1 ,2 ]
Stagni, Stefano [3 ]
Ogden, Mark I. [1 ,2 ]
机构
[1] Curtin Univ, Dept Chem, Kent St, Bentley, WA 6102, Australia
[2] Curtin Univ, Curtin Inst Funct Mol & Interfaces, Kent St, Bentley, WA 6102, Australia
[3] Univ Bologna, Dept Ind Chem Toso Montanari, Viale Risorgimento 4, I-40136 Bologna, Italy
基金
澳大利亚研究理事会;
关键词
Lanthanoid; Tetrazole; NITROGEN-RICH COMPOUNDS; SITU HYDROTHERMAL SYNTHESIS; CARBOXYLIC-ACID ISOSTERES; SINGLE-MOLECULE MAGNET; PH DEPENDENT SYNTHESIS; CRYSTAL-STRUCTURES; STRUCTURAL-CHARACTERIZATION; CATALYTIC-PROPERTY; LIGAND SYNTHESIS; METAL COMPLEXES;
D O I
10.1016/j.ccr.2017.11.017
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
While tetrazole derivatives are well established as anionic ligands for d-block elements, there is a growing interest in lanthanoid complexes of these compounds. Diverse structural chemistry results from the presence of four potential donor N atoms, and the conjugated nature of the heterocycle can impact on the photophysical properties of the complexes. This review examines the range of structurally characterised lanthanoid-tetrazolato complexes, focussing on the structural features of the ligand that impact on the tendency to interact with the first or second coordination spheres. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:164 / 172
页数:9
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