Polarization conductance of the electrode system O2,Au/0.9ZrO2-0-1Y2O3

被引：0
|
作者：
Shkerin, SN [1 ]
Vlasova, YL [1 ]
机构：
[1] Russian Acad Sci, Inst High Temp Electrochem, Ural Div, Ekaterinburg 620219, Russia
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2004年 / 40卷 / 08期
关键词：
yttria stabilized zirconium dioxide; surface electrolyte layer; interphase processes;
D O I：
10.1023/B:RUEL.0000037953.39916.bc
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
An impedancemetry method is employed to investigate a porous gold electrode in contact with a solid oxygen-conducting electrolyte on the basis of zirconium dioxide of the same cationic composition, whose samples differ in the oxygen content. Upon reaching a stationary state, the interphase oxygen exchange rate is independent of the previous treatment and oxygen stoichiometry of the sample. The results are linked to the existence on the electrolyte surface of a layer whose structure differs from the bulk structure.
引用
收藏
页码：860 / 863
页数：4
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