One-pot amination of cage hydrocarbons

被引:27
|
作者
Leonova, M. V. [1 ]
Skomorokhov, M. Yu. [1 ]
Moiseev, I. K. [1 ]
Klimochkin, Yu. N. [1 ]
机构
[1] Samara State Tech Univ, Ul Molodogvardeiskaya 244, Samara 443100, Russia
基金
俄罗斯科学基金会;
关键词
ADAMANTANE DERIVATIVES; RITTER REACTION; NITRIC-ACID; AMANTADINE; MEMANTINE; AMINOADAMANTANES; REDUCTION; DESIGN; AZIDES;
D O I
10.1134/S1070428015120064
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A one-pot procedure has been proposed for the synthesis of amines directly from cage hydrocarbons. A number of cage amines have been synthesized by treatment of adamantane, its homologs, and structurally related cage hydrocarbons with nitric acid in acetic acid and subsequent addition of urea and heating.
引用
收藏
页码:1703 / 1709
页数:7
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