Silver(I) coordination polymers using thioether macrocycle building blocks

被引:46
|
作者
Blake, AJ [1 ]
Champness, NR [1 ]
Howdle, SM [1 ]
Webb, PB [1 ]
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
关键词
D O I
10.1021/ic991145d
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
[Ag-2(hfpd)(2)([14]aneS(4))(infinity), and [Ag(hfpd)([9]aneS(3))(infinity), form one-dimensional coordination polymers in which the polymeric nature of the complexes is generated by one of the thioether donors adopting unusual bridging modes to link metal centers. The strongly coordinating hfpd anions act to inhibit polymer propagation.
引用
收藏
页码:1035 / +
页数:5
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