Reversible hydrogen storage in yttrium aluminum hydride

被引：31

作者：

Cao, Zhijie ^{[1
,2
,3
]}

Ouyang, Liuzhang ^{[1
,2
,4
]}

Wang, Hui ^{[1
,2
]}

Liu, Jiangwen ^{[1
,2
]}

Felderhoff, Michael ^{[3
]}

Zhu, Min ^{[1
,2
]}

机构：

[1] South China Univ Technol, Key Lab Adv Energy Storage Mat Guangdong Prov, Sch Mat Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China

[2] South China Univ Technol, China Australia Joint Lab Energy & Environm Mat, Guangzhou 510641, Guangdong, Peoples R China

[3] Max Planck Inst Kohlenforsch, Kaiser Wilhelm Pl 1, D-45470 Mulheim, Germany

[4] Key Lab Fuel Cell Technol Guangdong Prov, Guangzhou 510641, Guangdong, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2017年 / 5卷 / 13期

基金：

中国国家自然科学基金;

关键词：

METAL-HALIDES; PRESSURE; ALLOYS; DECOMPOSITION; LIALH4; PERFORMANCE; MG(ALH4)(2); ALANATE;

D O I：

10.1039/c6ta10928d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reversible hydrogen storage has been found in transition metal alanates, Y(AlH4)(3), for the first time. An amount of 3.4 wt% H-2 can be released at 140 degrees C fromthe first dehydrogenation step of Y(AlH4)(3), and 75% of it is reversible at 145 degrees C and 100 bar H-2, which holds promise for low- temperature applications.

引用

页码：6042 / 6046

页数：5

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