Formate-Mediated Cross-Electrophile Reductive Coupling of Aryl Iodides and Bromopyridines

被引：8
|
作者：
Schwartz, Leyah A. [1 ]
Spielmann, Kim [1 ]
Swyka, Robert A. [1 ]
Xiang, Ming [1 ]
Krische, Michael J. [1 ]
机构：
[1] Univ Texas Austin, Dept Chem, Welch Hall,105 E 24th St, Austin, TX 78712 USA
来源：
ISRAEL JOURNAL OF CHEMISTRY | 2021年 / 61卷 / 5-6期
关键词：
cross-electrophile coupling; reductive coupling; rhodium; palladium; formate; C BOND FORMATION; BIPHENYL SYNTHESIS; ALKYL BROMIDES; PALLADIUM; HALIDES; HYDROGEN; CHEMISTRY; CATALYSIS; KINETICS; BIARYLS;
D O I：
10.1002/ijch.202000069
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two catalytic systems for the formate-mediated cross-electrophile reductive coupling of aryl iodides with 6-bromopyridines are described. Using homogenous rhodium or heterogeneous palladium catalysts, the products of reductive biaryl cross-coupling could be formed in moderate yield with excellent levels of chemoselectivity.
引用
收藏
页码：298 / 301
页数：4
相关论文
共 50 条
  • [31] Nickel-catalyzed cross-electrophile coupling of aryl chlorides with allylic alcohols
    Yu, Hang
    Wang, Zhong-Xia
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 19 (44) : 9723 - 9731
  • [32] Ni-Catalyzed Formal Cross-Electrophile Coupling of Alcohols with Aryl Halides
    Lin, Quan
    Ma, Guobin
    Gong, Hegui
    ACS CATALYSIS, 2021, 11 (22) : 14102 - 14109
  • [33] Nickel-Catalyzed Cross-Electrophile Coupling of Triazine Esters with Aryl Bromides
    Liu, Xiang
    He, Cai-Yu
    Yin, Hao-Nan
    Miao, Chengping
    Chu, Xue-Qiang
    Rao, Weidong
    Xu, Hao
    Zhou, Xiaocong
    Shen, Zhi-Liang
    CHINESE JOURNAL OF CHEMISTRY, 2023, 41 (24) : 3539 - 3546
  • [34] Nickel-Catalyzed Asymmetric Propargyl-Aryl Cross-Electrophile Coupling
    Ding, Linlin
    Zhao, Yue
    Lu, Hongjian
    Shi, Zhuangzhi
    Wang, Minyan
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (01)
  • [35] Nickel-catalyzed cross-electrophile coupling of unactivated (hetero)aryl sulfone with aryl bromide
    Li, Wen-Xin
    Huo, Bo-Jie
    Huang, Jie-Ying
    Rao, Weidong
    Xu, Hao
    Zhou, Xiaocong
    Shen, Zhi-Liang
    JOURNAL OF CATALYSIS, 2024, 430
  • [36] Cross-Electrophile Coupling: Principles of Reactivity and Selectivity
    Everson, Daniel A.
    Weix, Daniel J.
    JOURNAL OF ORGANIC CHEMISTRY, 2014, 79 (11): : 4793 - 4798
  • [37] Magnesium-Mediated Reductive Defluorinative Cross-Electrophile Coupling of α-Trifluoromethyl Styrenes with CO2 and Acyl Imidazoles
    Hao, Jianjun
    Ren, Lu
    Tan, Jingwen
    Peng, Yulin
    Jing, Linhai
    Han, Pan
    ADVANCED SYNTHESIS & CATALYSIS, 2025, 367 (06)
  • [38] Selective Cross-Electrophile Coupling by Dual Catalysis
    Hanna, Luke E.
    Jarvo, Elizabeth R.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (52) : 15618 - 15620
  • [39] Iron-Catalyzed Cross-Electrophile Coupling
    Semenya, Julius
    Yang, Yuanjie
    Picazo, Elias
    SYNLETT, 2024,
  • [40] Branched-Selective Cross-Electrophile Coupling of 2-Alkyl Aziridines and (Hetero)aryl Iodides Using Ti/Ni Catalysis
    Williams, Wendy L.
    Gutierrez-Valencia, Neyci E.
    Doyle, Abigail G.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (44) : 24175 - 24183
12345