Non-covalent sulfoxide•••(nitrosyl group) interactions involving coordinated nitrosyl in a Ru(II) nitrosyl complex with an α-diimine ligand: structural and computational studies

被引：3

作者：

Kia, Reza ^{[1
]}

机构：

[1] Sharif Univ Technol, Chem Dept, POB 11155-3516, Tehran, Iran

来源：

CRYSTENGCOMM | 2020年 / 22卷 / 44期

关键词：

PI-ASTERISK INTERACTIONS; NITRIC-OXIDE; CARBONYL;

D O I：

10.1039/d0ce01063d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Investigation of the X-ray structure of the newly prepared [Ru(NO)((2,6isop)Ph(2)Aceq)Cl-3] ((2,6isop)Ph(2)Aceq = bis(2,6-diisopropylphenylimino)acenaphthenequinone) complex revealed for the first time the pi-hole interaction involving the coordinated nitrosyl group with DMSO as the solvent of crystallization in the crystal lattice. Processing of CSD data showed only one reported structure. A significant feature of the structure is the presence of n -> pi*, pi -> sigma*, and n -> sigma* interactions due to the coordinated nitrosyl and chloro groups and DMSO.

引用

页码：7532 / 7537

页数：6

共 13 条

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