A Facile Regioselective Synthesis of Novel Spiroacenaphthene Pyrroloisoquinolines Through 1,3-Dipolar Cycloaddition Reactions

被引：6

作者：

Sarrafi, Yaghoub ^{[1
]}

Asghari, Asieh ^{[1
]}

Hamzehloueian, Mahshid ^{[2
]}

Alimohammadi, Kamal ^{[3
]}

Sadatshahabi, Marzieh ^{[1
]}

机构：

[1] Univ Mazandaran, Fac Chem, Dept Organ Chem, Babol Sar 47416, Iran

[2] Islamic Azad Univ, Jouybar Branch, Dept Chem, Jouybar, Iran

[3] Univ Farhangian, Dr Shariati Branch, Dept Chem, Sari, Iran

来源：

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY | 2013年 / 24卷 / 12期

关键词：

1,3-dipolar cycloaddition; azomethine ylide; 1,5]-H shift; spiroacenaphthene pyrroloisoquinolines; AZOMETHINE YLIDE CYCLOADDITION; CONSTRUCTION; AZIRIDINES;

D O I：

10.5935/0103-5053.20130245

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient one-pot three-component procedure for the synthesis of novel spiroacenaphthene pyrroloisoquinolines with high regioselectivity is described. These compounds were prepared from 1,3-dipolar cycloaddition of an azomethine ylide generated from acenaphthenequinone and 1,2,3,4-tetrahydroisoquinoline via [1,5]-H shift, with chalcone and nitrostyrene derivatives as dipolarophiles. The structure and stereochemistry of the cycloadducts have been established by single crystal X-ray structure and spectroscopic techniques.

引用

页码：1957 / +

页数：64

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