Synthesis and characterization of CoSBA-1 cubic mesoporous molecular sieves

被引:67
|
作者
Vinu, A
Dedecek, J
Murugesan, V
Hartmann, M
机构
[1] Univ Kaiserslautern, Dept Chem, D-67653 Kaiserslautern, Germany
[2] Anna Univ, Dept Chem, Madras 600025, Tamil Nadu, India
[3] Acad Sci Czech Republ, Heyrovsky Inst Phys Chem, CZ-18223 Prague 8, Czech Republic
关键词
D O I
10.1021/cm025544+
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cobalt-substituted SBA-1 cubic mesoporous molecular sieves have been synthesized in the presence of the cationic surfactant cetyltriethylammonium bromide. UV-vis spectra revealed that the majority of the cobalt ions in the CoSBA-1 samples are present in a highly dispersed state and occupy framework position (Co-(II) is present in trigonal pyramidal coordination) in the surface layer of the CoSBA-1 channel walls.
引用
收藏
页码:2433 / +
页数:4
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