Regioselective synthesis and complexation behavior of novel [60]fullerene bisadducts containing dibenzo-18-crown-6 moiety

被引：29
|
作者：
Nakamura, Y
Asami, A
Inokuma, S
Ogawa, T
Kikuyama, M
Nishimura, J
机构：
[1] Gunma Univ, Dept Chem, Kiryu, Gumma 3768515, Japan
[2] Univ Air, Biol Lab, Mihama Ku, Chiba 2618586, Japan
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 13期
基金：
日本学术振兴会;
关键词：
fullerenes; Diels-Alder reaction; regioselective synthesis; crown ethers; complexation;
D O I：
10.1016/S0040-4039(00)00134-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of [60]fullerene with bis-o-quinodimethane precursor 3 containing a dibenzo-18-crown-6 moiety provided preferentially trans-4 bisadduct 5a along with a small amount of cis-2 bisadduct 5b. These bisadducts showed different ionophoric properties from each other; 5a exhibited a high complexing ability toward K+ ion, while 5b hardly showed complexation with any alkali metal ions. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2193 / 2197
页数：5
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