Self-Assembled Monolayers of Cyclohexyl-Terminated Phosphonic Acids as a General Dielectric Surface for High-Performance Organic Thin-Film Transistors

被引:101
|
作者
Liu, Danqing [1 ]
He, Zikai [1 ]
Su, Yaorong [2 ]
Diao, Ying [3 ]
Mannsfeld, Stefan C. B. [4 ]
Bao, Zhenan [3 ]
Xu, Jianbin [2 ]
Miao, Qian [1 ,5 ]
机构
[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
[2] Chinese Univ Hong Kong, Dept Elect Engn, Shatin, Hong Kong, Peoples R China
[3] Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA
[4] SLAC Natl Accelerator Lab, Menlo Pk, CA 94025 USA
[5] Chinese Univ Hong Kong, Ctr Novel Funct Mol, Shatin, Hong Kong, Peoples R China
关键词
self-assembled monolayers (SAMs); organic thin-film transistors; interface engineering; FIELD-EFFECT TRANSISTORS; STRUCTURAL-CHARACTERIZATION; OXIDE SURFACES; SEMICONDUCTORS; PENTACENE; ORDER; C-60; PHOSPHATIDYLCHOLINES; FABRICATION; MORPHOLOGY;
D O I
10.1002/adma.201402822
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel self-assembled monolayer (SAM) on AlOy/TiOx is terminated with cyclohexyl groups, an unprecedented terminal group for all kinds of SAMs. The SAM-modified AlOy/TiOx functions as a general dielectric, enabling organic thin-film transistors with a field-effect mobility higher than 5 cm2 V-1 s-1 for both holes and electrons, good air stability with low operating voltage, and general applicability to solution-processed and vacuum-deposited n-type and p-type organic semiconductors. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:7190 / 7196
页数:7
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