Synthesis, crystal structures and luminescence properties of two metal carboxyphosphonates

被引：2
|
作者：
Wang, Chaonan [1 ]
Feng, Pingjing [1 ]
Li, Jintang [1 ]
Luo, Xuetao [1 ]
机构：
[1] Xiamen Univ, Coll Mat, Fujian Prov Key Lab Adv Mat, Xiamen, Fujian Province, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2017年 / 249卷
基金：
中国国家自然科学基金;
关键词：
Metal phosphonates; 5-phosphononicotinic acid; 4-(hydroxy(phosphono)methyl)benzoic acid; Luminescence; MOLECULAR RECOGNITION PROPERTIES; SURFACE PHOTOVOLTAGE; PHOSPHONATES; FRAMEWORK; ZINC;
D O I：
10.1016/j.jssc.2017.02.019
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two metal carboxyphosphonates, [Co-2(OOCC5H3NPO3)(2)center dot(H2O)(3)] (Compoundl) and Zn-3[OOCC6H3CH(OH)PO3](2)center dot 2H(2)O (Compound2) were successfully synthesized under the hydrothermal reactions. In compound 1, two {Col-NO5} octahedra link the {CPO3} by sharing the corner, which link the two {Co2-O-6} octahedra. From a-axis the six clusters form the layer. Each layer is linked through hydrogen bond. In compound 2, the {Zn-O-4} tetrahedron and {CPO3} tetrahedron are corner-shared, which arrange in line. From a-axis, each line forms the columnar. The thermal and luminescence properties of these compounds were investigated.
引用
收藏
页码：136 / 140
页数：5
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