Synthesis, crystal structures, and luminescent properties of tin(II) and lead(II) carboxyphosphonates with 3D framework structures

被引：5
|
作者：
Zhou, Wei [1 ]
Zhang, Jing [2 ]
Sun, Zhen-Gang [1 ]
Zhu, Yan-Yu [1 ]
Jiao, Cheng-Qi [1 ]
Shi, Shao-Ping [1 ]
Dai, Lu-Lu [1 ]
Sun, Tong [1 ]
Li, Wen-Zhu [1 ]
Ma, Ming-Xue [1 ]
Luo, Hui [1 ]
机构：
[1] Liaoning Normal Univ, Sch Chem & Chem Engn, Dalian 116029, Peoples R China
[2] Shenyang Aerosp Univ, Thermal Energy Res Ctr, Shenyang 110136, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 47卷
基金：
中国国家自然科学基金;
关键词：
Metal phosphonates; Crystal structure; Luminescent property; Tin; Lead; CLUSTERS; SERIES;
D O I：
10.1016/j.inoche.2014.07.010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new metal carboxyphosphonates with 3D framework structures, [Sn-2(HL)center dot 2H(2)O] (1) and [Pb2Cl(H2L)] (2) (H5L = 4-HOOCC6H4CH2N(CH2PO3H2)(2)), have been synthesized under hydrothermal conditions. For compound 1, every two Sn(1)O-3 and Sn(2)O-3 polyhedra are linked by CPO3 tetrahedra to form a 2D inorganic layer via corner-sharing in the bc-plane. Then the adjacent layers are further assembled into a 3D supramolecular structure through pi-pi stacking interactions. Compound 2 features a 3D open-framework structure. The Pb(1)O5Cl, Pb(2)O-5 polyhedra and CPO3 tetrahedra are interconnected into a 20 inorganic layer via corner-sharing in the ac-plane. Such layers are further connected through carboxyphosphonate ligands to form a 3D open-framework structure. The luminescent properties of compounds 1 and 2 have also been studied. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：37 / 41
页数：5
相关论文
共 50 条
  • [1] Zinc(II) and cadmium(II) carboxyphosphonates with a 3D pillared-layered structure: synthesis, crystal structures, high thermal stabilities and luminescent properties
    Chu, Wei
    Zhu, Yan-Yu
    Sun, Zhen-Gang
    Jiao, Cheng-Qi
    Li, Jing
    Sun, Shou-Hui
    Tian, Hui
    Zheng, Ming-Jing
    [J]. RSC ADVANCES, 2013, 3 (02): : 623 - 631
  • [2] Two novel cadmium(II) carboxyphosphonates with 3D framework structure: synthesis, crystal structures, luminescence and molecular recognition properties
    Ma, Chao
    Jiao, Cheng-Qi
    Sun, Zhen-Gang
    Zhu, Yan-Yu
    Zhang, Xiao-Wen
    Wang, Mei-Ling
    Yang, Dan
    Zhao, Zhou
    Li, Huan-Yu
    Xing, Bo
    [J]. RSC ADVANCES, 2015, 5 (96): : 79041 - 79049
  • [3] Two novel lead(II) carboxyphosphonates with a layered and a 3D framework structure: syntheses, crystal structures, reversible dehydration/hydration, and luminescence properties
    Chu, Wei
    Sun, Zhen-Gang
    Jiao, Cheng-Qi
    Zhu, Yan-Yu
    Sun, Shou-Hui
    Tian, Hui
    Zheng, Ming-Jing
    [J]. DALTON TRANSACTIONS, 2013, 42 (22) : 8009 - 8017
  • [4] Synthesis, structures, surface photovoltage and luminescence properties of two new nickel(II) carboxyphosphonates with a 3D framework structure
    Luo, Hui
    Zhu, Yan-Yu
    Sun, Zhen-Gang
    Jiao, Cheng-Qi
    Zhang, Guang-Ning
    Sun, Tong
    Ma, Ming-Xue
    Li, Wen-Zhu
    [J]. RSC ADVANCES, 2014, 4 (91) : 49892 - 49899
  • [5] Two nickel(II) carboxyphosphonates with different supramolecular structures: synthesis, crystal structures and magnetic properties
    Zhu, Yan Yu
    Zhang, Xu
    Zhou, Ya Nan
    Sun, Zhen Gang
    Jiao, Cheng Qi
    [J]. TRANSITION METAL CHEMISTRY, 2021, 46 (08) : 593 - 600
  • [6] Two nickel(II) carboxyphosphonates with different supramolecular structures: synthesis, crystal structures and magnetic properties
    Yan Yu Zhu
    Xu Zhang
    Ya Nan Zhou
    Zhen Gang Sun
    Cheng Qi Jiao
    [J]. Transition Metal Chemistry, 2021, 46 : 593 - 600
  • [7] Syntheses, crystal structures, surface photovoltage, luminescence and molecular recognition properties of zinc(II) and iron(II) carboxyphosphonates with 2D and 3D supramolecular structures
    Zhou, Wei
    Zhu, Yan-Yu
    Jiao, Cheng-Qi
    Sun, Zhen-Gang
    Shi, Shao-Ping
    Dai, Lu-Lu
    Sun, Tong
    Li, Wen-Zhu
    Ma, Ming-Xue
    Luo, Hui
    [J]. CRYSTENGCOMM, 2014, 16 (06): : 1174 - 1186
  • [8] Syntheses, crystal structures, and luminescent properties of three zinc carboxyphosphonates with 2D layered and 3D pillared-layer structures
    Li, Hai-Qing
    Wang, Peng
    Ma, Yun-Sheng
    Cheng, Hong-Jian
    Tang, Xiao-Yan
    Xie, Ji-Min
    Yuan, Rong-Xin
    [J]. INORGANICA CHIMICA ACTA, 2015, 429 : 252 - 256
  • [9] Syntheses, structures and luminescent properties of cadmium(II) and silver(I) carboxyphosphonates with 2D supramolecular and layered structures
    Sun, Tong
    Li, Wenzhu
    Ma, Chao
    Sun, Zhengang
    Zhu, Yanyu
    Ma, Mingxue
    Luo, Hui
    Zhang, Xiaowen
    Wang, Meiling
    [J]. SOLID STATE SCIENCES, 2015, 41 : 8 - 13
  • [10] Hydrothermal synthesis, structures, and luminescent properties of zinc(II) and cadmium(II) phosphonates with a 3D framework structure using terephthalate as second linkers
    Tong, Fei
    Sun, Zhen-Gang
    Chen, Kai
    Zhu, Yan-Yu
    Wang, Wei-Nan
    Jiao, Cheng-Qi
    Wang, Cheng-Lin
    Li, Chao
    [J]. DALTON TRANSACTIONS, 2011, 40 (18) : 5059 - 5065
12345