Versatile Solvothermal Synthetic Method and Structural Characterization of Lithium Coordination Networks

被引：2

作者：

Jiang, Zhi-Qiang ^{[1
,2
]}

Du, Yu ^{[2
]}

Zhu, Xue-Jun ^{[2
]}

Lu, Jin ^{[2
]}

Huang, Zai-Chun ^{[2
]}

Li, Yu-Feng ^{[2
]}

Kang, Yao ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Panzhihua Univ, Deep Proc Fine Flake Grapgite Sichuan Prov Key La, Panzhihua 617000, Sichuan, Peoples R China

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2019年 / 29卷 / 05期

关键词：

Coordination polymer; Lithium; Structural diversity; Solvothermal synthesis; METAL-ORGANIC FRAMEWORKS; POLYMERS; CONSTRUCTION; TOPOLOGIES; DIVERSITY; CLUSTERS; LIGANDS; ROUTES; SIZE;

D O I：

10.1007/s10904-019-01108-0

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The reactions of LiOHH2O with 1,3,5-benzenetricarboxylic acid (1,3,5-btc) under versatile solvothermal conditions produce a series of lithium coordination polymers, namely {[Li-2(1,3,5-btc)(1,3,5-Hbtc)(DMF)](DMF)(2)}(n) (1), {[Li-3(1,3,5-btc)(DMSO)(3)](H2O)}(n) (2), {((CH3)(2)NH)[Li-2(1,3,5-btc)(H2O)]}(n) (3), {((CH3)(2)NH)[Li-2(1,3,5-btc)(1,3,5-Hbtc)]}(n) (4), {((CH3)(2)NH)[Li-2(1,3,5-btc)]}(n) (5) and [Li-3(1,3,5-btc)(H2O)](n) (6) (DMSO=dimethyl sulphoxide, DMF=N,N-dimethylformamide). Compound 1 and 4 exhibit two-dimensional framework, while compound 2, 3, 5 and 6 show three-dimensional network. The results demonstrate different solvents or different temperatures can generate the structural diversity. [GRAPHICS] .

引用

页码：1447 / 1456

页数：10

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