Versatile Solvothermal Synthetic Method and Structural Characterization of Lithium Coordination Networks

被引：2
|
作者：
Jiang, Zhi-Qiang [1 ,2 ]
Du, Yu [2 ]
Zhu, Xue-Jun [2 ]
Lu, Jin [2 ]
Huang, Zai-Chun [2 ]
Li, Yu-Feng [2 ]
Kang, Yao [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Panzhihua Univ, Deep Proc Fine Flake Grapgite Sichuan Prov Key La, Panzhihua 617000, Sichuan, Peoples R China
来源：
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2019年 / 29卷 / 05期
关键词：
Coordination polymer; Lithium; Structural diversity; Solvothermal synthesis; METAL-ORGANIC FRAMEWORKS; POLYMERS; CONSTRUCTION; TOPOLOGIES; DIVERSITY; CLUSTERS; LIGANDS; ROUTES; SIZE;
D O I：
10.1007/s10904-019-01108-0
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The reactions of LiOHH2O with 1,3,5-benzenetricarboxylic acid (1,3,5-btc) under versatile solvothermal conditions produce a series of lithium coordination polymers, namely {[Li-2(1,3,5-btc)(1,3,5-Hbtc)(DMF)](DMF)(2)}(n) (1), {[Li-3(1,3,5-btc)(DMSO)(3)](H2O)}(n) (2), {((CH3)(2)NH)[Li-2(1,3,5-btc)(H2O)]}(n) (3), {((CH3)(2)NH)[Li-2(1,3,5-btc)(1,3,5-Hbtc)]}(n) (4), {((CH3)(2)NH)[Li-2(1,3,5-btc)]}(n) (5) and [Li-3(1,3,5-btc)(H2O)](n) (6) (DMSO=dimethyl sulphoxide, DMF=N,N-dimethylformamide). Compound 1 and 4 exhibit two-dimensional framework, while compound 2, 3, 5 and 6 show three-dimensional network. The results demonstrate different solvents or different temperatures can generate the structural diversity. [GRAPHICS] .
引用
收藏
页码：1447 / 1456
页数：10
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