Characterization by Scanning Precession Electron Diffraction of an Aggregate of Bridgmanite and Ferropericlase Deformed at HP-HT

Scanning precession electron diffraction is an emerging promising technique for mapping phases and crystal orientations with short acquisition times (10-20 ms/pixel) in a transmission electron microscope similarly to the Electron Backscattered Diffraction (EBSD) or Transmission Kikuchi Diffraction (TKD) techniques in a scanning electron microscope. In this study, we apply this technique to the characterization of deformation microstructures in an aggregate of bridgmanite and ferropericlase deformed at 27 GPa and 2,130 K. Such a sample is challenging for microstructural characterization for two reasons: (i) the bridgmanite is very unstable under electron irradiation, (ii) under high stress conditions, the dislocation density is so large that standard characterization by diffraction contrast are limited, or impossible. Here we show that detailed analysis of intracrystalline misorientations sheds some light on the deformation mechanisms of both phases. In bridgmanite, deformation is accommodated by localized, amorphous, shear deformation lamellae whereas ferropericlase undergoes large strains leading to grain elongation in response to intense dislocation activity with no evidence for recrystallization. Plastic strain in ferropericlase can be semiquantitatively assessed by following kernel average misorientation distributions. Plain Language Summary We present a microstructural characterization of a mineralogical assemblage of the lower mantle deformed in the pressure-temperature conditions of the upper most lower mantle. We show that the magnesium silicate perovskite named bridgmanite is stiffer and deforms only along very localized shear bands. The magnesium oxide ferropericlase is much more ductile and takes most of the plastic strain.