Benzene hydrogenation over polydopamine-modified MCM-41 supported Ruthenium-Lanthanum catalyst

被引：4

作者：

Liao, Hongguang ^{[1
]}

Xiao, Yanjuan ^{[1
]}

Yu, Xiaoguang ^{[1
]}

Liu, Xuanyan ^{[1
]}

Zhong, Hongmei ^{[1
]}

Liang, Meidong ^{[1
]}

He, Haoyan ^{[1
]}

机构：

[1] Hunan Chem Vocat Technol Coll, Coll Chem Engn, Zhuzhou 412000, Hunan, Peoples R China

来源：

INORGANIC AND NANO-METAL CHEMISTRY | 2018年 / 48卷 / 12期

关键词：

Benzene hydrogenation; cyclohexene; polydopamine-modified MCM-41; hydrophilicity; ruthenium-lanthanum catalyst; SELECTIVE HYDROGENATION; UNDERWATER SUPEROLEOPHOBICITY; CYCLOHEXENE; RU; PERFORMANCE; NANOPARTICLES; ZN; OXIDATION; SIZE; ADDITIVES;

D O I：

10.1080/24701556.2019.1567539

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Polydopamine-modified MCM-41 was prepared by sodium periodate-induced polymerization. Ru-La supported on MCM-41 and polydopamine-modified MCM-41 catalysts were prepared by double solvent impregnation method and tested for benzene hydrogenation to cyclohexene. Polydopamine-modified MCM-41 supported Ru-La catalyst exhibits much higher hydrophilicity and more moderate catalytic activity than unmodified MCM-41 supported Ru-La catalyst. The higher hydrophilicity, more moderate catalytic activity, and long-range order of mesoporous structure are beneficial for improving cyclohexene selectivity on account of the promotion of the desorption and the inhibition of the adsorption of cyclohexene. 47.0% of cyclohexene yield was obtained over Ru-La supported on polydopamine-modified MCM-41 in benzene hydrogenation.

引用

下载

页码：599 / 606

页数：8

共 50 条

[21] Carbon dioxide hydrogenation catalyzed by ruthenium complexes immobilized on MCM-41
Yu, Ying-Min
Fei, Jin-Hua
Zhang, Yi-Ping
Zheng, Xiao-Ming
Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2006, 34 (06): : 700 - 705
[22] MCM-41 bound ruthenium complex as heterogeneous catalyst for hydrogenation I: Effect of support, ligand and solvent on the catalyst performance
Yu Ying-Min
Fei Jin-Hua
Zhang Yi-Ping
Zheng Xiao-Ming
CHINESE JOURNAL OF CHEMISTRY, 2006, 24 (07) : 840 - 844
[23] Benzylation of benzene over sulfated zirconia supported in MCM-41 using a single source precursor
Al-Hazmi, Mohammed H.
Apblett, Allen W.
CATALYSIS SCIENCE & TECHNOLOGY, 2011, 1 (04) : 621 - 630
[24] Ruthenium Catalysts Templated on Mesoporous MCM-41 Type Silica and Natural Clay Nanotubes for Hydrogenation of Benzene to Cyclohexane
Glotov, Aleksandr
Vutolkina, Anna
Pimerzin, Aleksey
Nedolivko, Vladimir
Zasypalov, Gleb
Stytsenko, Valentine
Karakhanov, Eduard
Vinokurov, Vladimir
CATALYSTS, 2020, 10 (05)
[25] Catalytic hydrogenation of corn stalk into polyol over Ni-W/MCM-41 catalyst
Pan, Guan-Yu
Ma, Yu-Long
Ma, Xiao-Xia
Sun, Yong-Gang
Lv, Jun-Min
Zhang, Jian-Li
CHEMICAL ENGINEERING JOURNAL, 2016, 299 : 386 - 392
[26] Fischer-Tropsch synthesis on iron catalysts supported on MCM-41 and MCM-41 modified with Cs.
Alvarez, AM
Bengoa, JF
Cagnoli, MV
Gallegos, NG
Yeramián, AA
Marchetti, SG
IMPACT OF ZEOLITES AND OTHER POROUS MATERIALS ON THE NEW TECHNOLOGIES AT THE BEGINNING OF THE NEW MILLENNIUM, PTS A AND B, 2002, 142 : 1339 - 1346
[27] Tungstophosphoric acid supported over zirconia in mesoporous channels of MCM-41 as catalyst in veratrole acetylation
Sawant, Dhanashri P.
Vinu, A.
Lefebvre, F.
Halligudi, S. B.
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 262 (1-2) : 98 - 108
[28] Hydrogenation of bisphenol A - Using a mesoporous silica based nano ruthenium catalyst Ru/MCM-41 and water as the solvent
Yen, Clive H.
Lin, Hsin Wei
Tan, Chung-Sung
CATALYSIS TODAY, 2011, 174 (01) : 121 - 126
[29] High enantioselectivity in the asymmetric hydrogenation of ketones by a supported Pt nanocatalyst on a mesoporous modified MCM-41 support
Basu, Susmit
CHINESE JOURNAL OF CATALYSIS, 2015, 36 (04) : 634 - 638
[30] HYDROGENATION OF BENZENE OVER NEW SUPPORTED RUTHENIUM CATALYSTS
ARAMENDIA, MA
BORAU, V
JIMENEZ, C
MARINAS, JM
GAZZETTA CHIMICA ITALIANA, 1987, 117 (01): : 39 - 42

← 1 2 3 4 5 →