Synthesis and post-polymerization modification of polynorbornene bearing dibromomaleimide side groups

被引：13
|
作者：
Li, Zi-Long [1 ]
Sun, Linhao [1 ]
Ma, Jimei [1 ]
Zeng, Zhen [1 ]
Jiang, Hong [1 ]
机构：
[1] Huazhong Agr Univ, Coll Sci, Dept Chem, Wuhan 430070, Hubei, Peoples R China
来源：
POLYMER | 2016年 / 84卷
基金：
中国国家自然科学基金;
关键词：
Polynorbornene; Dibromomaleimide; Post-polymerization modification; OPENING METATHESIS POLYMERIZATION; CLICK REACTIONS; POLYMERS; ROMP; FUNCTIONALIZATION; FLUORESCENT; DITHIOMALEIMIDE; BIOCONJUGATION; BACKBONE; COVALENT;
D O I：
10.1016/j.polymer.2016.01.020
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We demonstrate that polynorbornene containing dibromomaleimide side group is a novel polymer platform for post-polymerization modification. Polymer P0 was obtained through ring-opening metathesis polymerization of monomer 2 by using Grubbs third generation catalyst. Subsequently, P0 was chemically modified with 1-butanethiol and benzyl mercaptan to generate P1 and P2, respectively. In this way, the dibromomaleimide units on polymer side chain were quantitatively converted to dithiolmaleimide moieties. All the polymer samples exhibited good thermal stability and relatively high glass transition temperature. Meanwhile, the effects of substituent and solvent on fluorescent properties of the polymers were elucidated. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：336 / 342
页数：7
相关论文
共 50 条
  • [41] Designing functionalized polymers through post-polymerization modification of side chain leucine-based polymer
    Maity, Tanmoy
    Paul, Soumya
    De, Priyadarsi
    EUROPEAN POLYMER JOURNAL, 2023, 199
  • [42] Synthetic upcycling of polyacrylates through organocatalyzed post-polymerization modification
    Easterling, Charles P.
    Kubo, Tomohiro
    Orr, Zachary M.
    Fanucci, Gail E.
    Sumerlin, Brent S.
    CHEMICAL SCIENCE, 2017, 8 (11) : 7705 - 7709
  • [43] Post-polymerization modification of polystyrenes using orthogonal click reactions
    Kwisnek, Luke
    Oakdale, James S.
    Fokin, Valery V.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [44] Post-polymerization modification of polypeptides to create new functional materials
    Kramer, Jessica R.
    Deming, Timothy J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [45] Post-polymerization modification based on reactive fluorinated polymers reaction
    Du, Yiying
    Zeng, Qiugui
    Yuan, Ling
    He, Lirong
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2021, 58 (08): : 521 - 538
  • [46] Post-polymerization modification reactions of poly(glycidyl methacrylate)s
    Muzammil, Ezzah M.
    Khan, Anzar
    Stuparu, Mihaiela C.
    RSC ADVANCES, 2017, 7 (88): : 55874 - 55884
  • [47] Precise synthesis of heterogeneous glycopolymers with well-defined saccharide motifs in the side chain via post-polymerization modification and recognition with lectin
    Liu, Meina
    Miao, Dengyun
    Wang, Xingyou
    Wang, Caiyun
    Deng, Wei
    JOURNAL OF POLYMER SCIENCE, 2020, 58 (15) : 2074 - 2087
  • [48] Blocked isocyanates: an efficient tool for post-polymerization modification of polymers
    Bode, Stefan
    Enke, Marcel
    Goerls, Helmar
    Hoeppener, Stephanie
    Weberskirch, Ralf
    Hager, Martin D.
    Schubert, Ulrich S.
    POLYMER CHEMISTRY, 2014, 5 (07) : 2574 - 2582
  • [49] Accessing functional materials through organocatalyzed post-polymerization modification
    Easterling, Charles
    Kubo, Tomohiro
    Orr, Zachary
    Sanchez, Jose
    Fanucci, Gail
    Sumerlin, Brent
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [50] Functional polymers via post-polymerization modification of poly(methionine)
    Gharakhanian, Eric
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
12345