Fabrication, characterization, transportation of ions and antibacterial potential of polystyrene based Cu3 (PO4)2/Ni3 (PO4)2 composite membrane

被引:13
|
作者
Arsalan, Mohd [1 ]
Rafiuddin [1 ]
机构
[1] Aligarh Muslim Univ, Dept Chem, Membrane Res Lab, Aligarh 202002, Uttar Pradesh, India
关键词
Composite material; Structural characterization; Teorell; Meyer and Siever method; Membrane potential; Charge density; EXCHANGE MEMBRANES; CHARGED MEMBRANES; BIPOLAR MEMBRANE; WATER SOLUTIONS; BEHAVIOR; SEPARATION; PROTON;
D O I
10.1016/j.jiec.2013.12.050
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel organic-inorganic composite membrane was successfully prepared by sol-gel process. Such composite membrane shows best thermal, mechanical and chemical stability as well as good ion exchange property. Structural configuration of membrane was confirmed by TEM, XRD and FTIR analysis while thermal properties examined by TGA/DTA and LCR analysis. Teorell, Meyer Siever, method was used to determine the theoretical values of potential. The observed potentials and charge densities seems to follow KCl < NaCl < LiCI and LiCl < NaCl < KCl order respectively. By potential observation transport number, mobility ratio, distribution coefficient, charge effectiveness and fixed charge density of ions were calculated very easily. (C) 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:3568 / 3577
页数:10
相关论文
共 50 条
  • [41] Functionalized magnetic lipase/Cu3(PO4)2 hybrid nanoflower: Synthesis, characterization, and enzymatic evaluation
    Anboo, Shamini
    Lau, Sie Yon
    Kansedo, Jibrail
    Yap, Pow-Seng
    Hadibarata, Tony
    Kamaruddin, Azlina Harun
    HELIYON, 2024, 10 (06)
  • [42] Oxygen evolution reaction activity of Ni3(PO4)2 and bimetallic Ni3M3(PO4)4 (M = Mn, Fe, Co): Insights from DFT and experimental validation
    Nuruzzahran, Muhammad Arkan
    Syaifullah, Dzaki Ahmad
    Mariani, Clara Caroline
    Fathurrahman, Fadjar
    Yuliarto, Brian
    Dipojono, Hermawan Kresno
    Almohamadi, Hamad
    Wella, Sasfan Arman
    Septiani, Ni Luh Wulan
    Saputro, Adhitya Gandaryus
    FUEL, 2025, 385
  • [43] Synthesis, characterization and thermal property of {Cu3(PO4)2•2H2O; Na3PO4; NaHSO4•H2O}
    Swain, Trilochan
    SOLAR ENERGY, 2018, 159 : 369 - 374
  • [44] THE CRYSTAL-STRUCTURE OF MONOCLINIC AG5CU3(PO4)2((PO4)H(PO4)) AND ITS RELATIONSHIP TO THE TRICLINIC SODIUM ANALOG
    EFFENBERGER, H
    PERTLIK, F
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1991, 194 (3-4): : 207 - 219
  • [45] Effects of NiMoO4 impregnation on the catalytic activity of Cu3 (PO4)2 in the conversion of isopropanol
    Ouchabi, Mbarka
    Baalala, Mohammed
    Elaissi, Abdelkrim
    Louilidi, Ilyasse
    Boukhlifi, Fatima
    Bensitel, Mohammed
    MOROCCAN JOURNAL OF CHEMISTRY, 2021, 9 (03):
  • [46] Structure characterization and magnetic behavior of NaNi4(PO4)3 and KMn4(PO4)3
    Daidouh, A
    Martinez, JL
    Pico, C
    Veiga, ML
    JOURNAL OF SOLID STATE CHEMISTRY, 1999, 144 (01) : 169 - 174
  • [47] Preparation and characterization of CaSiO3-Ca3(PO4)2 composite bioceramics
    Ni, Siyu
    Chang, Jiang
    Lin, Kaili
    Zhai, Wanyin
    BIOCERAMICS, VOL 19, PTS 1 AND 2, 2007, 330-332 : 451 - +
  • [48] Gases released during the conversion of NH4Zr2(PO4)3 to HZr2(PO4)3
    Oi, T
    Horio, K
    Kikuchi, R
    Takahashi, H
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2001, 65 (01): : 305 - 308
  • [49] SUPERIONIC CONDUCTORS LI3FE2(PO4)3, LI3SC2(PO4)3, LI3CR2(PO4)3 - SYNTHESIS, STRUCTURE AND ELECTROPHYSICAL PROPERTIES
    BYKOV, AB
    CHIRKIN, AP
    DEMYANETS, LN
    DORONIN, SN
    GENKINA, EA
    IVANOVSHITS, AK
    KONDRATYUK, IP
    MAKSIMOV, BA
    MELNIKOV, OK
    MURADYAN, LN
    SIMONOV, VI
    TIMOFEEVA, VA
    SOLID STATE IONICS, 1990, 38 (1-2) : 31 - 52
  • [50] Gases Released During the Conversion of NH4Zr2(PO4)3 to HZr2(PO4)3
    T. Oi
    K. Horio
    R. Kikuchi
    H. Takahashi
    Journal of Thermal Analysis and Calorimetry, 2001, 65 : 305 - 308