Interconversion between Molecular Polyhedra and Metal-Organic Frameworks

被引：271

作者：

Li, Jian-Rong ^{[1
]}

Timmons, Daren J. ^{[1
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 18期

基金：

美国国家科学基金会;

关键词：

CRYSTAL-STRUCTURE; FUNCTIONALIZATION; ADSORPTION; DESIGN; CAGES; H-2;

D O I：

10.1021/ja901731z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The construction of a metal-organic framework (MOF) with a pcu-a topology using a preassembled soluble molecular octahedron has been realized experimentally. The resulting MOF can also be reversibly converted to the molecular octahedron. All such conversions are based on axial-ligand substitution reactions on the molecular octahedron.

引用

页码：6368 / +

页数：3

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