Isolation and lability of optically active telluronium imides

被引：0

作者：

Shimizu, T ^{[1
]}

Machida, Y ^{[1
]}

Kamigata, N ^{[1
]}

机构：

[1] Tokyo Metropolitan Univ, Dept Chem, Grad Sch Sci, Hachioji, Tokyo 1920397, Japan

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 2002卷 / 14期

关键词：

absolute configuration; circular dichroism spectra; optically active compounds; racemization; telluronium imides;

D O I：

10.1002/1099-0690(200207)2002:14<2265::AID-EJOC2265>3.0.CO;2-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active telluronium imides have been isolated for the first time, by optical resolution of their racemic samples on an optically active column by medium-pressure column chromatography. The relationship between absolute configuration and their optical properties was clarified, and the mechanism for their racemization was also studied. (C) Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.

引用

页码：2265 / 2267

页数：3

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