Metal-Organic Framework-Activated Carbon Composite Materials for the Removal of Ammonia from Contaminated Airstreams

被引:51
|
作者
McHugh, Lauren N. [1 ]
Terracina, Angela [2 ]
Wheatley, Paul S. [1 ]
Buscarino, Gianpiero [2 ]
Smith, Martin W. [3 ]
Morris, Russell E. [1 ]
机构
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[2] Univ Palermo, Dipartimento Fis & Chim, I-3690123 Palermo, Italy
[3] Dstl Porton Down, CBR Div, Salisbury SP4 0JQ, Wilts, England
基金
英国工程与自然科学研究理事会;
关键词
activated carbons; gas adsorption; metal-organic frameworks; porous materials; water stability; HKUST-1; ADSORPTION; STABILITY; CAPTURE; WATER;
D O I
10.1002/anie.201905779
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metal-organic frameworks (MOFs) are a class of porous materials that show promise in the removal of toxic industrial chemicals (TICs) from contaminated airstreams, though their development for this application has so far been hindered by issues of water stability and the wide availability and low cost of traditionally used activated carbons. Here a series of three MOF-activated carbon composite materials with different MOF to carbon ratios are prepared by growing STAM-17-OEt crystals inside the commercially available BPL activated carbon. The composite materials display excellent water stability and increased uptake of ammonia gas when compared to unimpregnated carbon. Such properties make these composites very promising in the fields of air purification and personal protective equipment.
引用
收藏
页码:11747 / 11751
页数:5
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