Overcoming the Voc limitation of CZTSe solar cells

被引：0

作者：

Risch, L. ^{[1
,2
]}

Vauche, L. ^{[1
,2
]}

Redinger, A. ^{[3
]}

Dimitrievska, M. ^{[4
]}

Sanchez, Y. ^{[4
]}

Saucedo, E. ^{[4
]}

Unold, T. ^{[3
]}

Goislard, T. ^{[1
]}

Ruiz, C. M. ^{[2
]}

Escoubas, L. ^{[2
]}

Simon, J. J. ^{[2
]}

机构：

[1] NEXCIS, Rousset, France

[2] Aix Marseille Univ, IM2NP, CNRS, UMR 7334, Marseille, France

[3] Helmholtz Zentrum Berlin Mat & Energie, Berlin, Germany

[4] IREC, Catalonia Inst Energy Res, Barcelona, Spain

来源：

2016 IEEE 43RD PHOTOVOLTAIC SPECIALISTS CONFERENCE (PVSC) | 2016年

关键词：

kesterite solar cells; CZTSe; V-oc deficit; secondary phases; defects; bandgap fluctuations; SECONDARY PHASES; IMPACT;

D O I：

暂无

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The V-oc deficit issue is considered to be the most significant limitation of high-performance kesterite devices [ 1]. Secondary phases, defects, band tailing and interface recombination at the kesterite/CdS heterojunction are possible reasons for the low Voc. Raman spectroscopy and PL imaging are applied here for the detection of these phenomena. Their impact on Voc and the efficiency of CZTSe devices is investigated. Process steps are optimized so as to limit their negative influence. Control of secondary phase removal and optimization of the CZTSe/CdS interface lead to significant Voc enhancement. CZTSe devices with 466 mV open circuit voltage and 8.2% power conversion efficiency are achieved. An even higher Voc of 490 mV is obtained for a 4.5% CZTSe/In2S3 device.

引用

页码：188 / 192

页数：5

共 50 条

[41] Extended FF-Voc parameterization for silicon solar cells
Bothe, Karsten
Hinken, David
Brendel, Rolf
2023 IEEE 50TH PHOTOVOLTAIC SPECIALISTS CONFERENCE, PVSC, 2023,
[42] Applicability of the Suns-VOC Method on Organic Solar Cells
Schiefer, Sebastian
Zimmermann, Birger
Glunz, Stefan W.
Wuerfel, Uli
IEEE JOURNAL OF PHOTOVOLTAICS, 2014, 4 (01): : 271 - 277
[43] Identification of factors reducing Voc in MC silicon solar cells
Breitenstein, O
Iwig, K
Konovalov, I
CONFERENCE RECORD OF THE TWENTY FIFTH IEEE PHOTOVOLTAIC SPECIALISTS CONFERENCE - 1996, 1996, : 453 - 456
[44] Mapping Voc in polycrystalline solar cells with nanoscale spatial resolution
Tennyson, Elizabeth M.
Garrett, Joseph L.
Munday, Jeremy N.
Leite, Marina S.
2016 IEEE 43RD PHOTOVOLTAIC SPECIALISTS CONFERENCE (PVSC), 2016, : 2289 - 2291
[45] Effect of Cu/(Zn plus Sn) ratio on the ZnSe position and performance of CZTSe solar cells
Kwon, Min-Su
Nam, Dahyun
Cheong, Hyeonsik
Jeon, Chan-Wook
JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 665 : 304 - 310
[46] Effects of Voltage-Bias Annealing on Metastable Defect Populations in CIGS and CZTSe Solar Cells
Harvey, Steven P.
Johnston, Steve
Teeter, Glenn
2016 IEEE 43RD PHOTOVOLTAIC SPECIALISTS CONFERENCE (PVSC), 2016, : 2169 - 2173
[47] Investigation on the Structure and Morphology of CZTSe Solar Cells by Adjusting Cu-Ge Buffer Layers
Han, Yanchen
Ao, Jianping
Zhang, Zhaojing
Gao, Qing
Guo, Jiajia
Liu, Wei
Liu, Fangfang
Zhang, Yi
ACS APPLIED ENERGY MATERIALS, 2021, 4 (10) : 11793 - 11801
[48] Formation of the front-gradient bandgap in the Ag doped CZTSe thin films and solar cells
Wang, Dongxiao
Wu, Jianyu
Liu, Xiyu
Wu, Li
Ao, Jianping
Liu, Wei
Sun, Yun
Zhang, Yi
JOURNAL OF ENERGY CHEMISTRY, 2019, 35 : 188 - 196
[49] Room-Temperature Surface Sulfurization for High-Performance Kesterite CZTSe Solar Cells
Wang, Siyu
Gao, Shoushuai
Wang, Dongxiao
Jiang, Zhenwu
Ao, Jianping
Zhou, Zhiqiang
Liu, Shengzhong
Sun, Yun
Zhang, Yi
SOLAR RRL, 2019, 3 (01)
[50] Overcoming the thermodynamic limitation in asymmetric hydrogen transfer reactions catalyzed by whole cells
Goldberg, Katja
Edegger, Klaus
Kroutil, Wolfgang
Liese, Andreas
BIOTECHNOLOGY AND BIOENGINEERING, 2006, 95 (01) : 192 - 198

← 1 2 3 4 5 →