Optical and electrical properties of Cu2ZnSnS4 thin films grown using spray pyrolysis technique and annealing in air

被引：14

作者：

Kim, Chan ^{[2
]}

Hong, Sungwook ^{[1
]}

机构：

[1] Daegu Univ, Div Sci Educ, Gyongsan 38453, Gyeongbuk, South Korea

[2] Kyungpook Natl Univ, Dept Phys, Daegu, South Korea

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2017年 / 645卷 / 01期

关键词：

CZTS; Cu2ZnSnS4; solar cell; thin film; annealing in air; spray pyrolysis; SOLAR-CELLS;

D O I：

10.1080/15421406.2016.1277653

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cu2ZnSnS4 (CZTS) thin films were manufactured using spray pyrolysis technique and annealed in air. The characteristics of these films manufactured at annealing temperatures of 350-550 degrees C in increments of 50 degrees C for annealing durations of 1, 2, and 3min were studied using X-ray diffraction, field-emission scanning electron microscopy (FE-SEM), ultraviolet-visible near-infrared (UV-Vis-NIR) spectrometer, and Hall effect measurements. Experimental results showed that the best CZTS film is a film annealed at 500 degrees C for 1min, which had moderate properties for manufacturing a solar cell device; its band gap energy, volume carrier concentration, mobility, and resistivity were 1.46eV, 1.22 x 10(19)cm(- 3), 1.963cm(-2)/Vs, and 0.283 cm, respectively.

引用

页码：217 / 224

页数：8

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