On the interaction between components of an alloy during its dissolution in the passive state

被引:3
|
作者
Alekseev, YV [1 ]
Plaskeev, AV [1 ]
机构
[1] Russian Federat, State Sci Ctr, Karpov Inst Phys Chem, Moscow 103064, Russia
来源
PROTECTION OF METALS | 2002年 / 38卷 / 04期
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1023/A:1019696814874
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
A thermodynamic model relating the anodic behavior of an alloy to its components' interaction is compared with experimental data on the anodic behavior of passive Fe-Cr alloys with different Cr content. For passive alloys containing 20 to 100 at. % of Cr, the theory well agree with the experiment, which allows to think of the alloy components' interaction in the mixed passive oxides as a factor determining the alloys' corrosion resistance in their passive state. In the alloys containing less than 20 at. % of Cr, the components' interaction is likely to manifest itself through their microstructural effect on the active centers on dissolving surface.
引用
收藏
页码:310 / 316
页数:7
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