user

Highly heteroselective ring-opening polymerization of rac-lactide initiated by bis(phenolato)scandium complexes

被引：250
|
作者：
Ma, Haiyan
Spaniol, Thomas P.
Okuda, Jun
机构：
[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany
[2] E China Univ Sci & Technol, Inst Appl Chem, Lab Organomet Chem, Shanghai 200237, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 46期
关键词：
lactides; ligand effects; polymerization; scandium; stereoselectivity;
D O I：
10.1002/anie.200603178
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Tactical response: High heterotactic stereocontrol was observed from the ring-opening polymerization of rac-lactide on using a series of bis(phenolato)scandium complexes (see scheme). This stereocontrol appears to involve a dynamic monomer-recognition process as a result of the interconversion of the configuration from Λ into Δ. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：7818 / 7821
页数：4
相关论文
共 50 条
  • [31] Synthesis of aluminum complexes containing salicylbenzoxazole ligands and their application in the ring-opening polymerization of rac-lactide
    Hormnirun, Pimpa
    Sumrit, Pattarawut
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [32] Aluminum complexes containing salicylbenzoxazole ligands and their application in the ring-opening polymerization of rac-lactide and ε-caprolactone
    Sumrit, Pattarawut
    Chuawong, Pitak
    Nanok, Tanin
    Duangthongyou, Tanwawan
    Hormnirun, Pimpa
    [J]. DALTON TRANSACTIONS, 2016, 45 (22) : 9250 - 9266
  • [33] Bench-stable potassium complexes for living and isoselective ring-opening polymerization of rac-lactide
    Ren, Fangping
    Li, Xinlei
    Xian, Ji
    Han, Xinning
    Cao, Luya
    Pan, Xiaobo
    Wu, Jincai
    [J]. JOURNAL OF POLYMER SCIENCE, 2022, 60 (20) : 2847 - 2854
  • [34] Ring opening polymerization of Rac-lactide using zinc amine-bis(phenolate) complexes
    Liu, Yi
    Kozak, Christopher
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
  • [35] Ring-opening polymerization of rac-lactide catalyzed by crown ether complexes of sodium and potassium iminophenoxides
    Wu, Bing-Bing
    Tian, Lu-Lu
    Wang, Zhong-Xia
    [J]. RSC ADVANCES, 2017, 7 (39): : 24055 - 24063
  • [36] Ring-opening polymerization of rac-lactide catalyzed by magnesium and zinc complexes supported by an NNO ligand
    Hu, Minggang
    Song, Xinfeng
    Wang, Fugui
    Zhang, Wenzhi
    Ma, Wenhui
    Han, Fuzhong
    [J]. NEW JOURNAL OF CHEMISTRY, 2022, 46 (03) : 1175 - 1181
  • [37] Studies on Multinuclear Magnesium tert-Butyl Heteroscorpionates: Synthesis, Coordination Ability, and Heteroselective Ring-Opening Polymerization of rac-Lactide
    Garces, Andres
    Sanchez-Barba, Luis F.
    Fernandez-Baeza, Juan
    Otero, Antonio
    Lara-Sanchez, Agustin
    Rodriguez, Ana M.
    [J]. ORGANOMETALLICS, 2017, 36 (04) : 884 - 897
  • [38] Aluminum complexes with bidentate amido ligands: synthesis, structure and performance on ligand-initiated ring-opening polymerization of rac-lactide
    Liu, Junpeng
    Ma, Haiyan
    [J]. DALTON TRANSACTIONS, 2014, 43 (24) : 9098 - 9110
  • [39] Sulfonamide-Supported Aluminum Catalysts for the Ring-Opening Polymerization of rac-Lactide
    Schwarz, Andrew D.
    Chu, Zengyong
    Mountford, Philip
    [J]. ORGANOMETALLICS, 2010, 29 (05) : 1246 - 1260
  • [40] Synthesis of mono(guanidinate) rare earth metal bis(amide) complexes and their performance in the ring-opening polymerization of L-lactide and rac-lactide
    Wang, Yibin
    Luo, Yunjie
    Chen, Jue
    Xue, Hanming
    Liang, Hongze
    [J]. NEW JOURNAL OF CHEMISTRY, 2012, 36 (04) : 933 - 940
12345