Highly heteroselective ring-opening polymerization of rac-lactide initiated by bis(phenolato)scandium complexes

被引：250
|
作者：
Ma, Haiyan
Spaniol, Thomas P.
Okuda, Jun
机构：
[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany
[2] E China Univ Sci & Technol, Inst Appl Chem, Lab Organomet Chem, Shanghai 200237, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 46期
关键词：
lactides; ligand effects; polymerization; scandium; stereoselectivity;
D O I：
10.1002/anie.200603178
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Tactical response: High heterotactic stereocontrol was observed from the ring-opening polymerization of rac-lactide on using a series of bis(phenolato)scandium complexes (see scheme). This stereocontrol appears to involve a dynamic monomer-recognition process as a result of the interconversion of the configuration from Λ into Δ. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：7818 / 7821
页数：4
相关论文
共 50 条
  • [1] Magnesium amino-bis(phenolato) complexes for the ring-opening polymerization of rac-lactide
    Devaine-Pressing, Katalin
    Lehr, Joshua H.
    Pratt, Michelle E.
    Dawe, Louise N.
    Sarjeant, Amy A.
    Kozak, Christopher M.
    [J]. DALTON TRANSACTIONS, 2015, 44 (27) : 12365 - 12375
  • [2] Controlled ring-opening polymerization of rac-lactide by titanium complexes
    Upitak, Kanokon
    Hormnirun, Pimpa
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [3] Rare-earth metal complexes supported by 1,ω-dithiaalkanediyl-bridged bis(phenolato) ligands:: Synthesis, structure, and heteroselective ring-opening polymerization of rac-lactide
    Ma, Haiyan
    Spaniol, Thomas P.
    Okuda, Jun
    [J]. INORGANIC CHEMISTRY, 2008, 47 (08) : 3328 - 3339
  • [4] Highly Selective and Immortal Magnesium Calixarene Complexes for the Ring-Opening Polymerization of rac-Lactide
    Walton, Mark J.
    Lancaster, Simon J.
    Redshaw, Carl
    [J]. CHEMCATCHEM, 2014, 6 (07) : 1892 - 1898
  • [5] Isoselective ring-opening polymerization of rac-lactide initiated by achiral heteroscorpionate zwitterionic zinc complexes
    Mou, Zehuai
    Liu, Bo
    Wang, Meiyan
    Xie, Hongyan
    Li, Ping
    Li, Lei
    Li, Shihui
    Cui, Dongmei
    [J]. CHEMICAL COMMUNICATIONS, 2014, 50 (77) : 11411 - 11414
  • [6] Highly Active Magnesium Initiators for Ring-Opening Polymerization of rac-Lactide
    Wang, Liying
    Ma, Haiyan
    [J]. MACROMOLECULES, 2010, 43 (16) : 6535 - 6537
  • [7] Highly heteroselective ring-opening polymerization of rac-lactide initiated by rare-earth alkoxides bearing chiral [NNOO]-type amine-bis(phenolate) ligands
    Duan, Yu-Lai
    Guo, Qian
    Liu, Gui-Yang
    Yi, Zhong-Zhou
    Feng, Shao-Ping
    Huang, Yong
    [J]. POLYMER CHEMISTRY, 2022, 13 (29) : 4249 - 4259
  • [8] Aluminum amine-(bis)phenolate complexes for ring-opening polymerization of rac-lactide and ε-caprolactone
    Cross, Edward D.
    Tennekone, Gayan K.
    Decken, Andreas
    Shaver, Michael P.
    [J]. GREEN MATERIALS, 2013, 1 (02) : 79 - 86
  • [9] Highly heteroselective ring-opening polymerization of racemic lactide initiated by divalent ytterbium complexes bearing amino bis(phenolate) ligands
    Yang, Sheng
    Du, Zhu
    Zhang, Yong
    Shen, Qi
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (78) : 9780 - 9782
  • [10] Stereoselective zwitterionic ring-opening polymerization of rac-lactide
    Si, Guifu
    Zhang, Shaojie
    Pang, Wenmin
    Wang, Fuzhou
    Tan, Chen
    [J]. POLYMER, 2018, 154 : 148 - 152
12345