Crystal structure of bis(O,O′-diisopropyl dithiophosphate):: [(C3H7O)2PS2]2

被引：0

作者：

Zhang, SS ^{[1
]}

Li, XM ^{[1
]}

Wang, JL ^{[1
]}

Wan, J ^{[1
]}

Jiao, K ^{[1
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2004年 / 20卷 / 02期

关键词：

X-ray crystallography; dithiophosphate; centrosymmetry;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal and molecular structures of [(C3H7O)(2)PS2](2)(CCDC No. 217201) were determined by means of X-ray crystallography. It crystallized in a triclinic system with space group P (1) over bar and lattice parameters a=0.82794(3) nm, b=0.84764(2) nm, c=0.85034(3) nm, alpha=97.78(3)degrees, beta=110.770(3)degrees, gamma=94.95(3)degrees, V=0.54701(9) nm(3), Z=1. In this molecule, the two diisopropyl dithiophosphate groups, [(C3H7O)(2)PS2](2), which are parallel to each other, are linked by an S-S bond and there exist inversion centers in the molecule. In the structure, the P = S bonds in the two dithiophosphate units are trans-oriented to each other.

引用

页码：146 / 148

页数：3

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