Catalytic Synthesis of Diphenolic Acid from Levulinic Acid over Bronsted Acidic Ionic Liquids

被引：0
|
作者：
Shen, Yue [1 ]
Sun, Jiankui [1 ]
Wang, Bo [1 ]
Xu, Feng [1 ]
Sun, Runcang [1 ,2 ]
机构：
[1] Beijing Forestry Univ, Coll Mat Sci & Technol, Beijing Key Lab Lignocellulos Chem, MOE Key Lab Wooden Mat Sci & Applicat, Beijing 100083, Peoples R China
[2] S China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Peoples R China
来源：
BIORESOURCES | 2014年 / 9卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Diphenolic acid; Levulinic acid; Ionic liquids; Condensation; Platform chemical; MESOPOROUS H3PW12O40-SILICA COMPOSITE; GAMMA-VALEROLACTONE; BIOMASS; CONVERSION; EFFICIENT;
D O I：
暂无
中图分类号：
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号：
0805 ; 080502 ; 0822 ;
摘要：
SO3H-based acidic ionic liquids were used as Bronsted acid catalysts for synthesis of diphenolic acid (DPA) from the condensation of phenol and levulinic acid, a platform chemical from renewable materials. Evidence is presented that the product with p,p'- and o,p'-isomers was obtained. Under the optimal conditions, the 93.2 mol% yield of DPA and close to 100% selectivity to p,p'-DPA were achieved in a process promoted by [BSMim]HSO4. The favorable results can be attributed to the special structures of ionic liquids and thiol compound involvement. Furthermore, a mechanism of condensation promoted by acidic ionic liquid with ethanethiol is proposed.
引用
收藏
页码：3264 / 3275
页数：12
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