One-pot synthesis of levulinic acid from cellulose in ionic liquids

被引：71
|
作者：
Shen, Yue [1 ]
Sun, Jian-Kui [1 ]
Yi, Yu-Xuan [1 ]
Wang, Bo [1 ]
Xu, Feng [1 ]
Sun, Run-Cang [1 ]
机构：
[1] Beijing Forestry Univ, Coll Mat Sci & Technol, Beijing Key Lab Lignocellulos Chem, Beijing 100083, Peoples R China
来源：
BIORESOURCE TECHNOLOGY | 2015年 / 192卷
基金：
中国国家自然科学基金;
关键词：
Cellulose; Degradation; Levulinic acid; Ionic liquids; CATALYTIC CONVERSION; ENZYMATIC-HYDROLYSIS; SELECTIVE CONVERSION; SOLVENT; EFFICIENT; SYSTEMS;
D O I：
10.1016/j.biortech.2015.05.080
中图分类号：
S2 [农业工程];
学科分类号：
0828 ;
摘要：
A simple and effective route for the production of levulinic acid (LA) from cellulose has been developed in SO3H-functionalized ionic liquids. The effects of ionic liquid structures, reaction conditions and combination of metal chlorides with ILs on the yield of LA were investigated, where the highest yield of 39.4% was obtained for 120 min in the presence of 1-(4-sulfonic acid) butyl-3-methylimidazolium hydrogen sulphate ([BSMim]HSO4) with addition of H2O. The catalytic activities of ionic liquids depended on the anions and decreased in the order: CF3SO3-> HSO4(-) > OAc-, which was in good agreement with their acidity order. The ILs play a dual solvent-acid role for the cellulose conversion into LA and exhibited favorable catalytic activity over four repeated runs. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：812 / 816
页数：5
相关论文
共 50 条
  • [1] One-pot synthesis of levulinic acid from cellulose in SO3H-functionalized ionic liquids
    Shen, Yue
    Sun, Jian
    Wang, Bo
    Xu, Feng
    Sun, Runcang
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [2] One-pot depolymerization of cellulose into glucose and levulinic acid by heteropolyacid ionic liquid catalysis
    Sun, Zhong
    Cheng, Mingxing
    Li, Huacheng
    Shi, Tian
    Yuan, Mengjia
    Wang, Xiaohong
    Jiang, Zijiang
    [J]. RSC ADVANCES, 2012, 2 (24) : 9058 - 9065
  • [3] Direct Production of Levulinic Acid in One Pot from Hemp Hurd by Dilute Acid in Ionic Liquids
    Tulaphol, Sarttrawut
    Hossain, Md Anwar
    Rahaman, Mohammad Shahinur
    Liu, Li-Yang
    Phung, Thanh Khoa
    Renneckar, Scott
    Grisdanurak, Nurak
    Sathitsuksanoh, Noppadon
    [J]. ENERGY & FUELS, 2020, 34 (02) : 1764 - 1772
  • [4] One-Pot Synthesis of 2,5-Furandicarboxylic Acid from Fructose in Ionic Liquids
    Yan, Dongxia
    Wang, Gongying
    Gao, Kai
    Lu, Xingmei
    Xin, Jiayu
    Zhang, Suojiang
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2018, 57 (06) : 1851 - 1858
  • [5] Sulphonic Acid-Functionalized Polymeric Ionic Liquids Catalyzed Conversion of Carbohydrates into Levulinic Acid in One-Pot Reaction
    Shi, Shengbin
    Wu, Wenting
    Liu, Panli
    Xiao, Guomin
    [J]. CHEMCATCHEM, 2023, 15 (05)
  • [6] One-Pot Synthesis of Levulinic Acid/Ester from CS Carbohydrates in a Methanol Medium
    Hu, Xun
    Song, Yao
    Wu, Liping
    Gholizadeh, Mortaza
    Li, Chun-Zhu
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2013, 1 (12): : 1593 - 1599
  • [7] One-pot construction of dihydropyrimidinones in ionic liquids
    Bahekar, SS
    Kotharkar, SA
    Shinde, DB
    [J]. MENDELEEV COMMUNICATIONS, 2004, 14 (05) : 210 - 212
  • [8] Straightforward one-pot synthesis of benzofuroxans from o-halonitrobenzenes in ionic liquids
    Sheremetev, Aleksei B.
    Aleksandrov, Nataliya S.
    Ignat'ev, Nikolai V.
    Schulte, Michael
    [J]. MENDELEEV COMMUNICATIONS, 2012, 22 (02) : 95 - 97
  • [9] One-pot and solventless synthesis of ionic liquids under ultrasonic irradiation
    Estager, Julien
    Leveque, Jean-Marc
    Cravotto, Giancarlo
    Boffa, Luisa
    Bonrath, Werner
    Draye, Micheline
    [J]. SYNLETT, 2007, (13) : 2065 - 2068
  • [10] Enzymatic Hydrolysis of Cellulose after Pretreated by Ionic Liquids: Focus on One-pot Process
    Zhi, Suli
    Liu, Yanli
    Yu, Xiaoyan
    Wang, Xinying
    Lu, Xuebin
    [J]. 2011 2ND INTERNATIONAL CONFERENCE ON ADVANCES IN ENERGY ENGINEERING (ICAEE), 2012, 14 : 1741 - 1747
12345