Synthesis, Structure and Photoluminescent Properties of [C6N2H14][Nd2(C2O4)2(SO4)2(H2O)4]•H2O, a New Organically Templated Neodymium(III) Oxalate-sulfate

被引：7
|
作者：
Xu, Ning [1 ]
Xing, Yan [1 ]
Liu, Xianchun [1 ]
Song, Danhui [1 ]
Ma, Ling [1 ]
Sun, Xiujuan [1 ]
机构：
[1] NE Normal Univ, Coll Chem, Changchun 130024, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2009年 / 635卷 / 03期
关键词：
Neodymium; Crystal engineering; Organic-inorganic hybrid composites; Luminescence; Open framework; COORDINATED ORGANONITROGEN LIGANDS; OPEN-FRAMEWORK STRUCTURES; RARE-EARTH SULFATES; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; PHOSPHITE; PILLARS; CHAINS; KAGOME; PHEN;
D O I：
10.1002/zaac.200801309
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An organically templated neodymium oxalate-sulfate [C6N2H14][Nd-2(C2O4)(2)(SO4)(2)(H2O)(4)]center dot H2O (1) has been synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction analysis. In 1, the neodymium(III) ions are interconnected through oxalate and sulfate groups to form a neodymium oxalate-sulfate hybrid structure. A luminescence spectrum of 1 was recorded, and the luminescence decay time was also measured.
引用
收藏
页码：558 / 562
页数：5
相关论文
共 50 条
  • [21] Hydrothermal synthesis and structure characterization of diamine-templated two-dimenisional cerium sulfate, [C6N2H14][Ce(SO4)2(H2O)2]•0.5SO4•2.5H2O
    Xin, MH
    Wang, Y
    Zhu, GS
    Sun, JY
    Xue, M
    Sun, FX
    Fang, QR
    Tian, G
    Qiu, SL
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2005, 21 (05) : 619 - 621
  • [22] Hydrothermal Synthesis and Structure Characterization of Diamine-templated Two-dimenisional Cerium Sulfate,[C6N2H14][Ce（SO4）2（H2O）2]·0·5SO4·2·5H2O
    XIN Ming-hong
    Chemical Research in Chinese Universities, 2005, (05) : 619 - 621
  • [23] Crystal structure of (C2H7N4O)2[UO2(C2O4)2(H2O)]
    I. V. Medrish
    E. V. Peresypkina
    A. V. Virovets
    L. B. Serezhkina
    Russian Journal of Coordination Chemistry, 2006, 32 : 910 - 914
  • [24] Synthesis,Properties and Crystal Structure of a New Bismuth Oxalate:Na（C5NH6）[Bi（H2O）(C2O4)2]2·4H2O
    陈新香
    曹彦宁
    张汉辉
    陈义平
    陈雪焕
    柴小川
    Chinese Journal of Structural Chemistry, 2008, (07) : 865 - 870
  • [25] Synthesis, properties and crystal structure of a new bismuth oxalate:: Na(C5NH6)[Bi(H2O)(C2O4)2]2•4H2O
    Chen Xin-Xiang
    Cao Yan-Ning
    Zhang Han-Hui
    Chen Yi-Ping
    Chen Xue-Huan
    Chai Xiao-Chuan
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 27 (07) : 865 - 870
  • [26] Crystal structure of (C2H7N4O)2[UO2(C2O4)2(H2O)]
    Medrish, I. V.
    Peresypkina, E. V.
    Virovets, A. V.
    Serezhkina, L. B.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2006, 32 (12) : 910 - 914
  • [27] Synthesis, Properties and Crystal Structure of a Novel Coordinated Polymer:{（H2en）(H3O)[(BiPb（C2O4）4（H2O）2)]·2（H2O）}n
    GUO Wen-Juna ZHANG Han-Huia
    Chinese Journal of Structural Chemistry, 2005, (07) : 846 - 850
  • [28] Synthesis, properties and crystal structure of a novel coordinated polymer:: {(H2en)(H3O)[(BiPb(C2O4)4(H2O)2)]•2(H2O)}n
    Guo, WJ
    Zhang, HH
    Huang, CC
    Sun, RQ
    Chen, YP
    Cao, YN
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (07) : 846 - 850
  • [29] Crystal structures of [Mn2(H2O)4(phen)2(C4H4O4)2] • 2 H2O and [Mn(phen)2(H2O)2][Mn(phen)2(C4H4O4)](C4H4O4) •7 H2O
    Zheng, YQ
    Lin, JL
    Sun, J
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (05): : 1059 - 1065
  • [30] Crystal structures, thermal analysis and IR investigations of (C4H14N2O)SO4 and (C4H14N2O)SO4 • H2O
    Guerfel, Taha
    Jouini, Amor
    MATERIALS RESEARCH BULLETIN, 2007, 42 (01) : 149 - 158
12345